Table 1. Conducting MOFs Prepared with Redox-Active Ligands.
| MOF | Formula | Dim | σ (S cm–1) | Ea (meV) | ref |
|---|---|---|---|---|---|
| 1-ox | (NBu4)2[FeIII2(dhbq)3] | 3D | 0.16a | 110 | (66) |
| 1-red | Na0.9(NBu4)1.8[FeIII2(dhbq)3] | 3D | 0.0062a | 180 | |
| 2-ox | (Me2NH2)2[Fe2(C6O4Cl2)3]·2H2O·6DMF | 2D | 1.4 × 10–2a | 260 | (64) |
| 2-red | (Cp2Co)1.43(Me2NH2)1.57[Fe2(C6O4Cl2)3]·4.9DMF | 2D | 5.1 × 10–4a | 340 | |
| 3-ox | (Me4N)2[Mn2(C6O4Cl2)3] | 2D | 1.14 × 10–13a | 740 | (67) |
| 3-red | Na3(Me4N)2[Mn2(C6O4Cl23–•)3]·3.9THF | 2D | 2.27 × 10–8a | 489 | |
| 3-reox | Na(Me4N)[Mn2(C6O4Cl2)3]·5.5THF·0.8CH3CN | 2D | 1.45 × 10–13a | – | |
| 4 | [CrIIICl2(pyz)•–]n | 2D | 0.032a | – | (69) |
| 5 | [VIICl2(pyz)]n | 2D | 10–10a | – | (70) |
| 6 | [TiIIICl2(pyz)•–]n | 2D | 5.3a | – | (70) |
a
Two-probe on pressed pellets.