Table 2. Conducting MOFs Prepared with Extended Conjugated Ligands.
# | Formula | Dim | σ (S cm–1) pressed pellet | σ (S cm–1) out-of-plane | σ (S cm–1) in-plane | Ea (meV) | ref. |
---|---|---|---|---|---|---|---|
7 | Cu3(HHB)2 | 2D | 7.3 × 10–8a | – | – | 450 | (71) |
8 | Cu3(HHTP)2 | 2D | 0.02–0.2b | 0.1b | – | – | (72−74) |
8-film | Cu3(HHTP)2 | 2D | – | – | 0.29c | 130 | (75) |
8-hex | Cu3(HHTP)2 | 2D | – | 1.5d | 0.5d | – | (76) |
9 | Cu3(HHTP)(HHB) | 2D | 2.53 × 10–5c | – | – | – | (77) |
10 | Co9(HHTP)4 | 2D | 0.1–0.003e | – | – | – | (78, 79) |
11 | Ni9(HHTP)4 | 2D | 0.01–3 × 10–6e | – | – | – | (78, 79) |
Four-probe.
Van der Pauw.
Two-probe (thin film).
Four- and two-probe on single crystals.
Electrochemical.