Table 6. Conducting MOFs with Mixed-Valence Metal Ions.

#	Complex	Redox couple	Dim	σ (S cm–1)	Ea (meV)	ref
25	Cu[Cu(pdt)2]	CuI/CuIII	3D	6 × 10–4a		(38)
44	[Cu3ICuIIBr3(3,5-Dmpip-dtc)2]n	CuI/CuII	2D	6.5 × 10–8b	380	(103)
45	[CuΙCu2ΙΙ(DCTP)2](NO3)·1.5DMF	CuI/CuII	3D	–	1050	(104)
46	Fe2(BDT)3	FeII/FeIII	3D	6 × 10–5a		(105)
46	Fe2(BDT)3 after 7 days	FeII/FeIII	3D	0.3a		(105)
46	Fe2(BDT)3 after 30 days	FeII/FeIII	3D	1.2a	160	(105)
47	[Fe(tri)2(BF4)0.33]	FeII/FeIII	3D	0.3c		(107)
48	[(H3O)(H2O)(phenazine)3] [FeIIFeIII(C6O4Cl2)3]·12H2O	FeII/FeIII	2D	0.03;a,d 1 × 10–4a,e	≈ 118	(55)
49	[(H3O)(H2O)(phenazine)3] [FeIIFeIII(C6O4Br2)3]·12H2O	FeII/FeIII	2D	0.003;a,d 1 × 10–5a,e	≈ 108	(55)

^aTwo-probe on single crystal.

^bImpedance on pressed pellet.

^cTwo-probe on pressed pellet.

^dParallel to the layers.

^ePerpendicular to the layers.