Table 7. Conducting MOFs with Cation Size and Electronic Structure Dependent Conductivity.
| # | Complex | r (Mn+) (pm) | Dim | σ (S cm–1) | Ea (meV) | ref |
|---|---|---|---|---|---|---|
| 50 | (H2NMe2)2[Ti2(C6O4Cl2)3] | 3D | 1 × 10–4a | 270 | (108) | |
| 51 | (H2NMe2)2[Cr2(C6O4Cl2)3] | 3D | 2.7 × 10–3a | 440 | (108) | |
| 52 | (H2NMe2)2[V2(C6O4Cl2)3] | 3D | 0.45a | 64 (300 K); 11 (20 K) | (108) | |
| 53 | Mn2(TTFTB) | 88 | 3D | 3.95 × 10–6b | (109) | |
| 54 | Co2(TTFTB) | 88.5 | 3D | 1.49 × 10–5b | (109) | |
| 55 | Zn2(TTFTB) | 97 | 3D | 8.64 × 10–5b | (109) | |
| 56 | Cd2(TTFTB) | 107 | 3D | 2.86 × 10–4b | (109) |
a
Two-probe on pressed pellet.
b
Two-probe on single crystal.