Table 8. Conducting MOFs Based on π···π Interactions.
# | Complex | Ligand | Dim | d (Å)a | σ (S cm–1) | ref |
---|---|---|---|---|---|---|
57 | [Cu2(4-ClBA)4(4,4′-bipy)]•DMF | 4-Cl-BA-H | 1D | 3.92 | 2.8 × 10–6b | (110) |
57-des | [Cu2(4-ClBA)4(4,4′-bipy)] | 4-Cl-BA-H | 1D | – | 3.9 × 10–6b | (110) |
58 | [Cu(ndc)(1,10-phen)] | 1,10-phen | 2D | 3.50 | 3 × 10–3b | (60) |
59 | [ZnNa2(ABEDBA)2(DEF)2]·DEF | H2ABEDBA | 3D | 3.4 | 1.3 × 10–3c | (111) |
60 | [Cd(DPNDI)(OH2)4](NO3)1.3·nDMA | DPNDI | 3D | 3.18 | 3.3 × 10–3c | (112) |
60-des | Cd(DPNDI)(OH2)4](NO3)1.3 | DPNDI | 3D | – | 3.7 × 10–2c | (112) |
61 | Cu(DPNDI)(PF6)2(DMA)4(CH3CN) | DPNDI | 3D | 3.7 | 1.2 × 10–5b | (113) |
62 | [Sr-(ntca)(H2O)2]·H2O | H4ntca | 2D | 3.4 | 10–4c | (114) |
Distance between neighboring π-ligands.
Four-probe on pressed pellet.
Two-probe on single crystal.