Table 2.
Pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) analysis of GTTE at 380 °C.
| No. | Rt (min)a | Compound | CAS No. | Content (%) b | SI c |
|---|---|---|---|---|---|
| 1 | 1.342 | Ethylamine | 75-12-7 | 16.73 | 94 |
| 2 | 1.415 | 5-Amino-6-nitroso-2,4(1H,3H)-pyrimidin | 0-00-0 | 7.02 | 95 |
| 3 | 1.466 | Ethanol | 64-17-5 | 10.45 | 97 |
| 4 | 1.565 | 3-oxo-Butanenitrile | 0-00-0 | 9.97 | 92 |
| 5 | 1.879 | 2,3-Butanedione | 431-03-8 | 2.04 | 98 |
| 6 | 2.048 | Acetic acid | 64-19-7 | 11.82 | 97 |
| 7 | 2.340 | Furan | 1708-29-8 | 0.45 | 79 |
| 8 | 2.390 | 1-hydroxy-2-Propanone | 116-09-6 | 4.77 | 98 |
| 9 | 2.717 | 2,3-Pentanedione | 600-14-6 | 0.48 | 95 |
| 10 | 2.810 | Propanoic acid | 79-09-4 | 0.26 | 83 |
| 11 | 2.878 | 3-hydroxy-2-Butanone | 513-86-0 | 0.43 | 95 |
| 12 | 2.920 | 2,4-Dimethylfuran | 3710-43-8 | 0.43 | 89 |
| 13 | 5.622 | 2-Furanmethanol | 98-00-0 | 0.91 | 96 |
| 14 | 5.904 | 1-(acetyloxy)-2-Propanone | 592-20-1 | 0.60 | 97 |
| 15 | 9.273 | Phenol | 108-95-2 | 0.58 | 95 |
| 16 | 10.055 | 5-Methyl-5,6-dihydro-2(1H)-pyridinone | 0-00-0 | 0.16 | 86 |
| 17 | 11.544 | Cyclopropyl carbinol | 2516-33-8 | 0.32 | 88 |
| 18 | 12.778 | Xanthine riboside | 146-80-5 | 0.36 | 89 |
| 19 | 14.444 | Methyl pentadecyl ether | 0-00-0 | 0.40 | 72 |
| 20 | 14.552 | 2-[(tetrahydro-2H-pyran-2-yl)oxy]- Propanoic acid | 87930-86-7 | 0.50 | 78 |
| 21 | 14.850 | 2,5-Monomethylene-l-rhamnitol | 0-00-0 | 0.31 | 68 |
| 22 | 17.425 | 1,1′-oxybis-Octane | 629-82-3 | 0.33 | 92 |
| 23 | 17.563 | 1-Tetradecanol | 112-72-1 | 0.37 | 86 |
| 24 | 18.291 | Octanoic acid, octyl ester | 2306-88-9 | 0.11 | 92 |
| 25 | 19.013 | Caffeine | 58-08-2 | 29.47 | 95 |
| 26 | 19.595 | Dibutyl phthalate | 84-74-2 | 0.39 | 95 |
| 27 | 20.412 | 1-Hexadecanol | 36653-82-4 | 0.11 | 92 |
| 28 | 20.935 | Propionic acid, 3,3′-thiodi-, didodecyl | 123-28-4 | 0.03 | 68 |
| 29 | 21.256 | Octanoic acid, 4-pentadecyl ester | 0-00-0 | 0.03 | 76 |
| 30 | 22.192 | Hexanedioic acid, bis(2-ethylhexyl) ester | 103-23-1 | 0.04 | 90 |
| 31 | 22.813 | Oxalic acid, 2-ethylhexyl isohexyl ester | 0-00-0 | 0.04 | 83 |
| 32 | 23.050 | Diisooctyl phthalate | 131-20-4 | 0.05 | 92 |
| 33 | 23.418 | Heptyl tetracosyl ether | 0-00-0 | 0.04 | 78 |
Note.
Rt, retention time of pyrolytic product.
The relative contents of pyrolytic products were calculated by peak area normalization, and results are expressed as the ratio of single constituent area to total area.
SI, index of similarity.