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. 2024 Feb 27;10(5):e27145. doi: 10.1016/j.heliyon.2024.e27145

Table 2.

Pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) analysis of GTTE at 380 °C.

No. Rt (min)a Compound CAS No. Content (%) b SI c
1 1.342 Ethylamine 75-12-7 16.73 94
2 1.415 5-Amino-6-nitroso-2,4(1H,3H)-pyrimidin 0-00-0 7.02 95
3 1.466 Ethanol 64-17-5 10.45 97
4 1.565 3-oxo-Butanenitrile 0-00-0 9.97 92
5 1.879 2,3-Butanedione 431-03-8 2.04 98
6 2.048 Acetic acid 64-19-7 11.82 97
7 2.340 Furan 1708-29-8 0.45 79
8 2.390 1-hydroxy-2-Propanone 116-09-6 4.77 98
9 2.717 2,3-Pentanedione 600-14-6 0.48 95
10 2.810 Propanoic acid 79-09-4 0.26 83
11 2.878 3-hydroxy-2-Butanone 513-86-0 0.43 95
12 2.920 2,4-Dimethylfuran 3710-43-8 0.43 89
13 5.622 2-Furanmethanol 98-00-0 0.91 96
14 5.904 1-(acetyloxy)-2-Propanone 592-20-1 0.60 97
15 9.273 Phenol 108-95-2 0.58 95
16 10.055 5-Methyl-5,6-dihydro-2(1H)-pyridinone 0-00-0 0.16 86
17 11.544 Cyclopropyl carbinol 2516-33-8 0.32 88
18 12.778 Xanthine riboside 146-80-5 0.36 89
19 14.444 Methyl pentadecyl ether 0-00-0 0.40 72
20 14.552 2-[(tetrahydro-2H-pyran-2-yl)oxy]- Propanoic acid 87930-86-7 0.50 78
21 14.850 2,5-Monomethylene-l-rhamnitol 0-00-0 0.31 68
22 17.425 1,1′-oxybis-Octane 629-82-3 0.33 92
23 17.563 1-Tetradecanol 112-72-1 0.37 86
24 18.291 Octanoic acid, octyl ester 2306-88-9 0.11 92
25 19.013 Caffeine 58-08-2 29.47 95
26 19.595 Dibutyl phthalate 84-74-2 0.39 95
27 20.412 1-Hexadecanol 36653-82-4 0.11 92
28 20.935 Propionic acid, 3,3′-thiodi-, didodecyl 123-28-4 0.03 68
29 21.256 Octanoic acid, 4-pentadecyl ester 0-00-0 0.03 76
30 22.192 Hexanedioic acid, bis(2-ethylhexyl) ester 103-23-1 0.04 90
31 22.813 Oxalic acid, 2-ethylhexyl isohexyl ester 0-00-0 0.04 83
32 23.050 Diisooctyl phthalate 131-20-4 0.05 92
33 23.418 Heptyl tetracosyl ether 0-00-0 0.04 78

Note.

a

Rt, retention time of pyrolytic product.

b

The relative contents of pyrolytic products were calculated by peak area normalization, and results are expressed as the ratio of single constituent area to total area.

c

SI, index of similarity.