Concentration dependences of diffusion coefficients (D) for TMS and 1, and average aggregation number (N) fora1.
| c[1], mM | c/cmax | D TMS, 10−9 m2 s−1 | D obs, 10−9 m2 s−1 | D TMS/Dobs | N |
|---|---|---|---|---|---|
| 3.74 | 1.00 | 3.36 | 0.651 | 5.16 | 3.89 |
| 2.79 | 0.75 | 3.37 | 0.781 | 4.31 | 2.27 |
| 1.83 | 0.49 | 3.38 | 0.797 | 4.24 | 2.16 |
| 1.46 | 0.39 | 3.38 | 0.860 | 3.93 | 1.72 |
| 1.16 | 0.31 | 3.38 | 0.855 | 3.95 | 1.75 |
| 1.00 | 0.27 | 3.38 | 0.918 | 3.68 | 1.41 |
From 400 MHz 1H NMR spectroscopy in acetone-d6 at 298 K.