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. 2024 Feb 12;15(11):4005–4018. doi: 10.1039/d3sc06941a

Concentration dependences of diffusion coefficients (D) for TMS and 1, and average aggregation number (N) fora1.

c[1], mM c/cmax D TMS, 10−9 m2 s−1 D obs, 10−9 m2 s−1 D TMS/Dobs N
3.74 1.00 3.36 0.651 5.16 3.89
2.79 0.75 3.37 0.781 4.31 2.27
1.83 0.49 3.38 0.797 4.24 2.16
1.46 0.39 3.38 0.860 3.93 1.72
1.16 0.31 3.38 0.855 3.95 1.75
1.00 0.27 3.38 0.918 3.68 1.41
a

From 400 MHz 1H NMR spectroscopy in acetone-d6 at 298 K.