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. 2024 Feb 2;15(11):4054–4067. doi: 10.1039/d3sc06552a

Comprehensive optical properties of polymers and monomersa.

Polymer/monomer M n/Mw (kDa) X n/Xw Yieldb (%) λ abs THF (nm) λ ex c (nm) λ em THF (nm) Stokes shift (nm)
PN4A 22/35 26/38 94 386 386 527 141
N4A 388 390 481 93
PN6P-Br 15/37 14/34 89 458 437 480 22
N6P-Br 470 442 479 9
PN6P-Bu 21/36 19/33 93 474 455 488 14
N6P-Bu 477 450 487 10
PN6P-Ph 20/36 18/32 90 485 460 496 11
N6P-Ph 485 455 495 10
a

Where Mn is the number average molecular weight, Mw is weight average molecular weight, Xn is number average degree of polymerization and Xw is weight average degree of polymerization. Polymer molecular weights were determined using gel permeation chromatography (tetrahydrofuran as the eluent) against polystyrene standards.

b

After Soxhlet extraction.

c

Excitation wavelength for reported emission spectra.