Comprehensive optical properties of polymers and monomersa.
| Polymer/monomer | M n/Mw (kDa) | X n/Xw | Yieldb (%) | λ abs THF (nm) | λ ex c (nm) | λ em THF (nm) | Stokes shift (nm) |
|---|---|---|---|---|---|---|---|
| PN4A | 22/35 | 26/38 | 94 | 386 | 386 | 527 | 141 |
| N4A | 388 | 390 | 481 | 93 | |||
| PN6P-Br | 15/37 | 14/34 | 89 | 458 | 437 | 480 | 22 |
| N6P-Br | 470 | 442 | 479 | 9 | |||
| PN6P-Bu | 21/36 | 19/33 | 93 | 474 | 455 | 488 | 14 |
| N6P-Bu | 477 | 450 | 487 | 10 | |||
| PN6P-Ph | 20/36 | 18/32 | 90 | 485 | 460 | 496 | 11 |
| N6P-Ph | 485 | 455 | 495 | 10 |
Where Mn is the number average molecular weight, Mw is weight average molecular weight, Xn is number average degree of polymerization and Xw is weight average degree of polymerization. Polymer molecular weights were determined using gel permeation chromatography (tetrahydrofuran as the eluent) against polystyrene standards.
After Soxhlet extraction.
Excitation wavelength for reported emission spectra.