PCET rate constants at pH 5.5 and 8.5 for 2MP-α₃C and 4MP-α₃C with [Ru(L)₃]³⁺ oxidants and their Ru^3+/2+ potentials.

Oxidant	pH	k PCET (M−1 s−1)	E°a (mV vs. NHE)
2MP-α 3 C
Ru(dmb)33+	5.5(±0.1)	2.8 × 103	+1100
Ru(bpy)33+	5.5(±0.1)	1.5 × 104	+1260
Ru(dmb)33+	8.5(±0.1)	7.7 × 105	+1100
Ru(bpy)33+	8.5(±0.1)	4.8 × 106	+1260
Ru(deeb)33+	8.5(±0.1)	3.2 × 107	+1540
4MP-α 3 C
Ru(dmb)33+	5.5(±0.1)	4.4 × 103	+1100
Ru(bpy)33+	5.5(±0.1)	2.1 × 104	+1260
Ru(dmb)33+	8.5(±0.1)	1.5 × 106	+1100
Ru(bpy)33+	8.5(±0.1)	6.1 × 106	+1260
Ru(deeb)33+	8.5(±0.1)	5.4 × 107	+1540

^aError bars are estimated to be ±30 mV.