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. 2024 Mar 18;14(13):9122–9136. doi: 10.1039/d4ra00674g

Ideal MFC components.

Ideal properties Effect on MFC performance References
Anode electrode
Conductivity Reduce resistance, improve electron transfer, lower losses 66 and 67
Improve electrochemical performance over plain carbon paper
Surface area Enhance bacterial attachment 68 and 69
More biocatalysts from organic compounds oxidation (e.g., graphite felt yields higher output power than a graphite rod because of its increased surface area)
Porosity and pore structure Maintain anoxic conditions for electricity generation in the anode 68 and 70
Large bio-accessible surface area
Thickness Minimise resistance to electron transport from the biofilm to the anode 71
Stability and durability pH shift tolerant conditions 72
Biocompatibility Facilitate bacteria–electrode interaction and higher biomass 73–75
Electro catalytic activity Enhancement on in situ oxidation of the microbial metabolites 76
Low cost Feasibility of scale-up and commercial application 77
Mechanical strength Better mechanical strength under a range of conditions by using carbonaceous and metallic materials (e.g., carbon paper, carbon rods, graphite felt, reticulated vitreous carbon, nickel sheets, stainless steel mesh, and copper sheets) 68
Cathode electrode
Conductivity Polarization loss reduction 78
Oxygen reduction reaction enhancement
Stability and durability pH shift tolerant 72
Low cost Feasibility of scale-up and commercial application 77
Catalytic activity Oxygen reduction reaction enhancement 74 and 79
Lower cathodic activation energy and increase the rate of reaction
Biocompatibility Improve the biocathode biocompatibility 78
Active sites Enhancement in number of active sites (e.g. pyridinic and pyrrolic nitrogen) to facilitate a more efficient transfer of electrons during the oxygen reduction reaction 74
Separator membrane
Stability To be resilient and stable in acidic and alkaline conditions 80
Conduction To conduct the protons to cathode, not electrons to fulfil the eqn (1) and (2) for energy generation 81
Impermeability to gases To allow H+ to pass from the anode to the cathode side and be impermeable to gases like H2, O2, and N2 82
Low cost Feasibility of scale-up and commercial application 80 and 83
Hydrophilicity To facilitate cationic transport and should also inhibit oxygen diffusion 84