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A: Structures of d‐sedoheptulose and designed deoxyfluorinated target compounds 4‐deoxy‐4‐fluoro‐d‐sedoheptulose (4DFS) and 3‐deoxy‐3‐fluoro‐d‐sedoheptulose (3DFS). B: Enzymatic transformations of d‐sedoheptulose‐7‐phosphate (S7P) during the non‐oxidative PPP; F6P=fructose‐6‐phosphate, E4P=erythrose‐4‐phosphate, G3P=glyceraldehyde‐3‐phosphate, R5P=ribose‐5‐phosphate, Xu5P=xylulose‐5‐phosphate, ThDP=thiamine diphosphate.
