Figure 1.

[A–C]: The utility of CF₂H groups, their synthesis and challenges; [D]: Electrochemical defluorination strategy. CV of 1 a–d (averaged forward and return currents). ‐Ni||+Pt, 5 mM [1 a–d], degassed DMF, 0.1 V/s, NBu₄PF₆, N₂. See Supporting Information for CVs run in with different electrode materials and in MeCN.