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. 2023 Apr 14;29(29):e202300008. doi: 10.1002/chem.202300008

Scheme 2.

Scheme 2

a) Paquette's study of the Ag(I)‐catalyzed rearrangement of TCH‐based structure 13. b) Adam's isotopic labeling approach to probing the relationship between bicyclo[1.1.0]butane inter ring angle and the mechanism of light‐induced rearrangement. Degree of deuteration shown as a percentage of available deuterium.