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. 2024 Mar 22;14(14):9725–9746. doi: 10.1039/d3ra08959b

EIS parameters for the corrosion of mild steel in 20% formic acid in the presence and absence of different concentrations of 8b and 2 mmol KI at 30 °C.

Conc. (ppm) KI (mmol) L (H cm2) R L (Ω cm2) R ct (Ω cm2) n C dl (μF cm−2) Z w × 10−3 (Ω cm2) η (%)
Blank 45.17 21.82 45.13 0.917 50.78
1 12.98 19.53 97.99 0.782 41.90 53.9
1 2 845.9 0.844 21.85 179.1 94.7
5 24.21 31.33 111.4 0.847 39.00 59.5
5 2 994.1 0.769 23.87 10.07 95.5
10 19.96 36.95 139.1 0.801 39.56 67.6
10 2 1015 0.756 22.96 8.772 95.6
20 29.16 36.59 154.9 0.839 37.70 70.9
20 2 1159 0.799 20.83 11.18 96.1
50 42.43 43.05 175.9 0.830 37.40 74.3
50 2 1381 0.760 42.21 8.038 96.7
100 38.71 47.15 192.1 0.785 42.06 76.5
100 2 1460 0.800 26.71 8.327 96.9