Table 2.

Arrhenius parameters for 2,3,3,3-Tetrafluoropropene decomposition model (ATⁿexp(−E/RT), units: mole, K, s, cm, kJ).

Reaction	A	n	E
CH2CFCF3 (+M)=>CF3+CH2:CF (+M) 7.9E+15		0.	451.9
LOW /5.40E18 0.0 108700.0/
H2O/9.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
CH3F /6.00/ CH2F2 /6.00/ CHF3 /6.00/ HF /2.00/
CF3CCH2 + F = CH2CFCF3	2.0e14	0.	0.
CH-CFCF3 + H = CH2CFCF3	2.0e14	0.	0.
CH2CFCF3 + H = CH-CFCF3 + H2	2.5e13	0.	66.9
CH2CFCF3 + H = CH2:CHF + CF3	1.5e13	0.	25.1
CH2CFCF3 + OH = CH-CFCF3 + H2O	2.e13	0.	28.5 *
CH2CFCF3 + OH = CH3 + CF3COF	7.5e11	0.	1.0 **
CH2CFCF3 + O = CH-CFCF3 + OH	1.2e12	0.7	62.8
CH2CFCF3 + O = CF3-CHF + HCO	1.3e7	1.83	0.
CH2CFCF3 + O = CH2F + CO + CF3	6.5e6	1.83	0.
CH2CFCF3 + CF3 = CH-CFCF3+CHF3	2.e13	0.	58.6
CH2CFCF3 + F = CH-CFCF3 + HF	5.e13	0.	30.1
CH2CFCF3 + F = CH2:CF2 + CF3	5.e13	0.	30.1
CH2CFCF3 + F = CHF:CHF[Z]+ CF3	5.e13	0.	30.1
CH-CFCF3 = CF3 + C2HF	2.1e13	0.	179.9
CH-CFCF3 + O2 = HO2 + CFCCF3	2.e13	0.	129.7
CH-CFCF3 + H = CF3 + CH2:CF	2.e13	0.	20.9
CH-CFCF3 + H = H2 + CFCCF3	1.e13	0.	12.6
CH-CFCF3 + H = HF + CF3CCH	1.e13	0.	8.4
CH-CFCF3 + OH = H2O + CFCCF3	2.e13	0.	0.
CH-CFCF3 + CH3 = CH4 + CFCCF3	1.e13	0.	33.5
CFCCF3 + H = CF3 + C2HF	5.e13	0.	31.4
CFCCF3 + O = CF3 + CFCO	1.1e13	0.	0.
CFCCF3 + OH = CF3 + CHFCO	3.e13	0.	20.9
CFCCF3 + F = CF3 + C2F2	1.e13	0.	29.3
*) [24] ; **) [25]