Table 1.

KM-SUB kinetic and experimental input parameters

Parameter	Lower boundary	Upper boundary	Description
$k_{\text{SLR}}$	1.0 $\times$ 10-15	1.0 $\times$ 10-8	Rate coefficient of OL+O3 surface reaction (cm3 s-1)
$k_{\text{BR}}$	1.0 $\times$ 10-20	1.0 $\times$ 10-11	Rate coefficient of OL+O3 bulk reaction (cm3 s-1)
$D_{\text{b,O3}}$	1.0 $\times$ 10-11	1.0 $\times$ 10-5	Bulk diffusion coefficient of ozone (cm2 s-1)
$D_{\text{b,OL}}$	1.0 $\times$ 10-12	1.0 $\times$ 10-6	Bulk diffusion coefficient of oleic acid (cm2 s-1)
$H_{\text{cp,O3}}$	5.0 $\times$ 10-6	5.0 $\times$ 10-3	Henry’s law solubility coefficient of ozone (mol cm-3 atm-1)
${\tau }_{\text{d,O3}}$	1.0 $\times$ 10-9	1.0 $\times$ 10-2	Desorption lifetime of O3 (s)
${\alpha }_{\text{s,0,O3}}$	1.0 $\times$ 10-4	1	Surface accommodation coefficient of ozone on an adsorbate-free surface ( )
$r_{\text{p}}$	2.5 $\times$ 10-6	1.0 $\times$ 10-3	Particle radius (cm)
${[{\text{O}}_3]}_{\text{g,0}}$	1.0 $\times$ 1011	1.0 $\times$ 1015	Initial gas phase number concentration of ozone (cm-3)
${[\text{OL}]}_{\text{b,0}}$	1.0 $\times$ 1019	2.0 $\times$ 1021	Initial bulk number concentration of oleic acid (cm-3)

The respective lower and upper boundaries indicate the initial constraints of the fit ensemble and an estimate of experimentally accessible conditions in a laboratory for atmospheric aerosol chemistry