. 2024 Mar 27;14(15):10244–10254. doi: 10.1039/d4ra01195c

Summary of the M–C_carbene bond lengths [Å], the C_carbene–M–C_carbene angle [°], the tilt of the NCN unit [°] of the complexes Pd/PtL3 and PdL9 and the C_bridge–M–C_bridge angle [°] for PdL9.

Compound	PdL3	PtL3	PdL9
M–C_carbene [Å]	2.038\|2.039	2.033\|2.039	2.019
C_carbene–M–C_carbene [°]	180	180	172.03
Tilt NCN unit [°]	55.30	50.53	53.62
C_bridge–M–C_bridge [°]	—	—	98.97

Summary of the M–Ccarbene bond lengths [Å], the Ccarbene–M–Ccarbene angle [°], the tilt of the NCN unit [°] of the complexes Pd/PtL3 and PdL9 and the Cbridge–M–Cbridge angle [°] for PdL9.