Table 3.
Thermodynamic parameters of the phase transition of DMPC MLVs (Tp, ΔT1/2, ΔHp, Tm, ΔT1/2 and ΔH), with increasing amounts of DMSO a.
XDMSO | % DMSO (v/v) | Tp/°C | ΔT1/2/°C | ΔHp kJ·mol−1 |
Tm /°C | ΔT1/2 /°C | ΔH kJ·mol−1 |
---|---|---|---|---|---|---|---|
0 | 0 | 13.1 | 2.3 | 2 | 23.9 | 0.6 | 21 |
0.027 | 10 | 15.8 | 2.2 | 3 | 24.6 | 0.6 | 22 |
0.060 | 20 | 18.2 | 1.6 | 2 | 25.5 | 0.6 | 22 |
0.098 | 30 | 24.2 | 1.3 | 2 | 27.5 | 0.6 | 18 |
0.14 | 40 | 26.0 | 1.0 | 2 | 28.3 | 0.6 | 16 |
a The estimated uncertainty is ±0.2 °C for the transition temperature, ±0.2 °C for the half width at half height, and ±1.5 kJ·mol−1 for ΔH.