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. 2024 Mar 12;14(3):371. doi: 10.3390/life14030371

Table 2.

Types of abiotic and biotic degradation of microplastics.

Degradation Degradation Methods Consequences of Degradation Ref.



Photodegradation
Visible, infrared, UV light

Reaction through light and reactive species involvement with a catalyst
- Chain scission
- Cross-linking
- Flexibility loss, color change

- Oxidative decomposition
- Generation of reactive oxygen species
- Complete mineralization to H2O, CO2
[25,26,27,28]







ABIOTIC



Thermal degradation



1. Identification of MPs by pyrolysis gas
2. High-temperature-production H, CO, CH4, or fuel oil
3. As a pretreatment technique for MP degradation at low temperatures
- Conformational changes
- Depolymerization of fragments

- Breakage of polymeric backbone, molecular deterioration, changes in tensile strength, alteration of crystallinity, reduction in durability, cracks and color changes
[29,30,31]
Hydrolytic degradation
(hydrogen ions in acidic or alkaline media)
- Chain breakage
- Surface corrosion of polyesters
- Cross-linking

- Chain breakage
- Chain breaking, formation of products
- Mineralization of MPs
[31,32]
Chemical degradation Oxidative degradation (heat, light, atmospheric oxygen)
Advanced oxidation processes
Bacterial degradation



- Enzymatic oxidation
- Hydrolysis
- Chain scission
[33,34,35]
Fungal degradation
BIOTIC Biodegradation Enzymatic biodegradation [36]
Combined biodegradation (by multiple bacteria) [36]
Algae degradation [37]