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. 2024 Mar 12;14(3):371. doi: 10.3390/life14030371

Table 3.

Examples of determination of polymers in various samples using different pretreatment techniques as well as methods for identification and detection.

Sample Polymers Sample Pretreatment Method Ref.
Water,
sediment
PES, PA, PS Catalytic wet peroxidation with H2O2,
NaClO, and Fenton reagents,
SEM, FTIR [80]
Sand PE, PET, PS, PA, PVC Wet peroxidation with H2O2
5.3 M NaCl
Filtration
μ-FTIR [81]
Sand, sediment PE, PS, PET, PP, PVC, Silicone, Nylon 6, Polyimide, Polysulfone Drying, sieving
Oxidation with H2O2 and Fenton reagents (H2O2 + Fe2+)
FTIR
Raman spectroscopy
[82]
Indoor dust PET, PA, PP, PE Digestion with 30% H2O2 and ZnCl2
Filtration through metal filter, sonication with ethanol
LDIR
LC-MS/MS
[83]
Surface water PE, PP, PS, PVC, PET, PDMS, CPE Oxidation with 30% H2O2 + 0.05 M FeSO4·7H2O
5 M NaCl
Filtration
Pyr-GC/MS
FTIR
[84]
Atmospheric aerosol
Atmospheric deposition
PET, PC Sieving, digestion, density separation, filtration, drying Microscope, SEM, FTIR, Raman spectroscopy, LC-MS/MS [85]
Surface water PE, PP Sieving, oxidation with 30% and 0.05 M Fe(II)
5 M NaCl
Filtration, drying
SEM, FTIR [86]
Marine fish
(gastrointestinal tract)
PET, PP, PAN, PE, PVAc, PA, PS, PB, PC Digestion with 10% KOH and 30% H2O2
Filtration, drying
SEM, FTIR [40]
Water, sediment, tadpoles PES, PP Digestion with 30% H2O2
Filtration, drying
SEM, FTIR [87]
Sea water LDPE, PA, PET, PVC Resuspension water SDS (150 g.L−1),
ultrasonication, filtration
Raman spectroscopy [88]
Indoor and outdoor air PC, PE, PET, PS, PVC, PP Raman spectroscopy [89]

SDS—sodium dodecylsulfate; PDMS—polydmethylsiloxane; CPE—chlorinated polyethylene, PVAc—polyvinyl acetate; PB—polybutene; LDPE—low-density polyethylene.