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. 2024 Mar 16;17(6):1369. doi: 10.3390/ma17061369

Table 3.

Kinetic parameters obtained by fitting experimental data for the adsorption of CLO and AMI on pMWCNTs and fMWCNTs using pseudo-first-order, pseudo-second-order, and Elovich models.

Pseudo-First-Order
Model
Pseudo-Second-Order
Model
Elovich Model
Adsorbate Adsorbent mads
(mg)
qeI
(mg/g)
kI
(min−1)
R 2 qeII
(mg/g)
kII
(g/(mg min))
R 2 α
(mg/(g min))
β
(mg/g)
R 2
CLO pMWCNTs 10 130.86 3.122 0.985 136.09 0.045 0.996 3.029 × 109 0.172 0.984
20 79.73 2.623 0.996 83.43 0.058 0.999 1.208 × 107 0.215 0.985
30 55.88 3.801 0.996 57.31 0.169 0.999 8.397 × 1012 0.565 0.993
40 43.71 5.833 0.999 44.08 0.687 0.999 2.062 × 1039 2.145 0.999
50 35.04 3.750 0.992 35.83 0.264 0.983 4.903 × 1012 0.903 0.990
fMWCNTs 10 50.23 0.732 0.999 52.98 0.023 0.986 4838.37 0.200 0.937
20 35.41 2.710 0.995 36.01 0.265 0.996 1.009 × 1016 1.116 0.998
30 31.20 1.126 0.994 32.25 0.086 0.999 8.693 × 107 0.669 0.994
40 27.88 1.514 0.998 28.60 0.161 0.999 6.375 × 1011 1.078 0.999
50 28.93 2.427 0.988 30.07 0.150 0.998 3.806 × 106 0.595 0.980
AMI pMWCNTs 10 99.93 0.807 0.906 106.20 0.013 0.970 2091.86 0.080 0.984
20 49.07 1.441 0.972 53.30 0.034 0.936 2571.26 0.175 0.985
30 36.42 0.851 0.941 38.98 0.034 0.987 1542.52 0.242 0.990
40 34.21 1.117 0.998 36.31 0.049 0.999 2401.26 0.272 0.968
50 34.80 1.117 0.936 37.11 0.047 0.899 1841.14 0.256 0.987
fMWCNTs 10 94.16 0.919 0.968 100.19 0.014 0.998 2789.45 0.089 0.966
20 80.28 0.706 0.993 86.03 0.012 0.980 641.93 0.088 0.899
30 57.88 1.302 0.980 60.90 0.039 0.999 1.153 × 106 0.223 0.986
40 42.80 1.857 0.998 44.93 0.069 0.995 82060.74 0.298 0.969
50 37.15 1.662 0.967 39.18 0.069 0.969 25894.01 0.313 0.978