Table 7.
The Uncertainty budget for pH of PVP-I solution.
| Sources of uncertainty | Unit | Value (x) | Uncertainty (u(x)) | Coverage factor (k) (95% CI) | Relative uncertainty (u(x)/x) |
|---|---|---|---|---|---|
| 0.5% PVP-I solution | |||||
| Balance | g | 5 | 0.002 | 2 | 0.0002 |
| V. Flask | mL | 1000 | 0.24 | 2 | 0.00012 |
| M. Cylinder | mL | 167 | 0.36 | 2 | 0.0011 |
| pH Meter | – | 4.86 | 0.002 | 2 | 0.00021 |
| Homogeneity | – | 4.896 | 0.002 | – | 0.00041 |
| Stability | – | 4.86 | 0.012 | – | 0.0025 |
| Repeatability | – | 4.86 | 0.02 | – | 0.0041 |
| Mean value | 4.86 | ||||
| Combined standard uncertainty | 0.024 | ||||
| Coverage factor (95% CI) | 2 | ||||
| Expanded uncertainty | 0.05 | ||||
| 0.6% PVP-I Solution | |||||
| Balance | g | 6 | 0.002 | 2 | 0.00017 |
| V. Flask | mL | 1000 | 0.24 | 2 | 0.00012 |
| M. Cylinder | mL | 167 | 0.36 | 2 | 0.0011 |
| pH Meter | – | 4.82 | 0.002 | 2 | 0.00021 |
| Homogeneity | – | 4.919 | 0.003 | – | 0.00061 |
| Stability | – | 4.82 | 0.0069 | – | 0.0014 |
| Repeatability | – | 4.82 | 0.02 | – | 0.0041 |
| Mean value | 4.82 | ||||
| Combined standard uncertainty | 0.02 | ||||
| Coverage factor (95% CI) | 2 | ||||
| Expanded uncertainty | 0.04 | ||||