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. 2024 Mar 15;29(6):1319. doi: 10.3390/molecules29061319

Table 3.

13C{1H} NMR nonequivalences (ΔΔδ, ppm, 150 MHz, CDCl3, 25 °C) for C-NO2, CONH, COOH and CH-α carbons of (S)-enantiomerically enriched mixtures of substrates 17 (15 mM) in the presence of 2 equiv of 1-TU and 1 equiv of DABCO and of (R)-enantiomerically enriched mixture of 8 (7.5 mM) in the presence of 4 equiv of 1-TU and 2 equiv of DABCO.

Sub ΔΔδ
COOH CONH C-NO2 CH-α
1 0.405 0.377 0.328 0.267
2 0.436 0.403 0.360 0.115
3 0.345 0.269 0.241 0.107
4 0.266 0.183 0.138 0.102
5 0.275 0.266 0.222 0.222
6 0.405 0.367 0.284 0.184
7 0.374 0.314 0.230 0.170
8 0 0.055 0.023 0