Table 3.
13C{1H} NMR nonequivalences (ΔΔδ, ppm, 150 MHz, CDCl3, 25 °C) for C-NO2, CONH, COOH and CH-α carbons of (S)-enantiomerically enriched mixtures of substrates 1–7 (15 mM) in the presence of 2 equiv of 1-TU and 1 equiv of DABCO and of (R)-enantiomerically enriched mixture of 8 (7.5 mM) in the presence of 4 equiv of 1-TU and 2 equiv of DABCO.
Sub | ΔΔδ | |||
---|---|---|---|---|
COOH | CONH | C-NO2 | CH-α | |
1 | 0.405 | 0.377 | 0.328 | 0.267 |
2 | 0.436 | 0.403 | 0.360 | 0.115 |
3 | 0.345 | 0.269 | 0.241 | 0.107 |
4 | 0.266 | 0.183 | 0.138 | 0.102 |
5 | 0.275 | 0.266 | 0.222 | 0.222 |
6 | 0.405 | 0.367 | 0.284 | 0.184 |
7 | 0.374 | 0.314 | 0.230 | 0.170 |
8 | 0 | 0.055 | 0.023 | 0 |