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. 2024 Mar 15;58(12):5461–5471. doi: 10.1021/acs.est.3c07161

Table 1. Summary of Polypropylene Microplastic Photochemical Degradation, Carbon Tracking, and Chemical Changes Initial, Final, and Percent Recovery of Plastic Mass, as well as Carbon Accounting of Plastic C as Plastic, DOC, or Purgeable Carbona.

  Plastic mass recovery
Carbon accounting
Irradiation time (days) Starting PP mass (g) Recovered PP mass (g) % of initial PP mass recovered PP % C by mass % of initial plastic-C recovered DOC accumulation (mg DOC g plastic-C–1) % of initial plastic-C as DOC % of initial plastic-C as purgeable-C
0 0.300 ± 0.001 0.296 ± 0.001 100.0 ± 0.5 90.4 ± 0.7 100.0 ± 1.0 0.114 ± 0.022 0.00 ± 0.00 0.00 ± 0.96
26 0.302 ± 0.001 0.292 ± 0.001 98.0 ± 0.5 88.4 ± 1.7 95.6 ± 1.8 0.89 ± 0.18 0.08 ± 0.02 3.98 ± 1.84
53 0.299 ± 0.001 N/A N/A N/A N/A 8.36 ± 0.18 0.82 ± 0.02 N/A
181 0.299 ± 0.001 0.253 ± 0.001 85.9 ± 0.4 86.8 ± 0.5 82.6 ± 0.2 82.09 ± 0.32 8.20 ± 0.03 9.17 ± 0.7
279 0.299 ± 0.001 0.233 ± 0.001 79.3 ± 0.4 85.8 ± 1.4 75.3 ± 1.3 123.0 ± 6.7 12.3 ± 0.67 12.4 ± 1.5
364 0.302 ± 0.001 0.215 ± 0.001 72.5 ± 0.4 85.9 ± 0.8 69.0 ± 0.8 172.9 ± 2.2 17.3 ± 0.22 13.7 ± 0.8
Dark 364 0.301 ± 0.001 0.295 ± 0.001 99.3 ± 0.5 90.1 ± 0.2 99.1 ± 0.6 0.129 ± 0.022 0.00 ± 0.00 0.92 ± 0.57
a

Plastic carbon content and DOC accumulation values included for carbon tracking. Missing data for day 56 is due to sample loss during analysis.