Table 1. Summary of Polypropylene Microplastic Photochemical Degradation, Carbon Tracking, and Chemical Changes Initial, Final, and Percent Recovery of Plastic Mass, as well as Carbon Accounting of Plastic C as Plastic, DOC, or Purgeable Carbona.
Plastic
mass recovery |
Carbon
accounting |
|||||||
---|---|---|---|---|---|---|---|---|
Irradiation time (days) | Starting PP mass (g) | Recovered PP mass (g) | % of initial PP mass recovered | PP % C by mass | % of initial plastic-C recovered | DOC accumulation (mg DOC g plastic-C–1) | % of initial plastic-C as DOC | % of initial plastic-C as purgeable-C |
0 | 0.300 ± 0.001 | 0.296 ± 0.001 | 100.0 ± 0.5 | 90.4 ± 0.7 | 100.0 ± 1.0 | 0.114 ± 0.022 | 0.00 ± 0.00 | 0.00 ± 0.96 |
26 | 0.302 ± 0.001 | 0.292 ± 0.001 | 98.0 ± 0.5 | 88.4 ± 1.7 | 95.6 ± 1.8 | 0.89 ± 0.18 | 0.08 ± 0.02 | 3.98 ± 1.84 |
53 | 0.299 ± 0.001 | N/A | N/A | N/A | N/A | 8.36 ± 0.18 | 0.82 ± 0.02 | N/A |
181 | 0.299 ± 0.001 | 0.253 ± 0.001 | 85.9 ± 0.4 | 86.8 ± 0.5 | 82.6 ± 0.2 | 82.09 ± 0.32 | 8.20 ± 0.03 | 9.17 ± 0.7 |
279 | 0.299 ± 0.001 | 0.233 ± 0.001 | 79.3 ± 0.4 | 85.8 ± 1.4 | 75.3 ± 1.3 | 123.0 ± 6.7 | 12.3 ± 0.67 | 12.4 ± 1.5 |
364 | 0.302 ± 0.001 | 0.215 ± 0.001 | 72.5 ± 0.4 | 85.9 ± 0.8 | 69.0 ± 0.8 | 172.9 ± 2.2 | 17.3 ± 0.22 | 13.7 ± 0.8 |
Dark 364 | 0.301 ± 0.001 | 0.295 ± 0.001 | 99.3 ± 0.5 | 90.1 ± 0.2 | 99.1 ± 0.6 | 0.129 ± 0.022 | 0.00 ± 0.00 | 0.92 ± 0.57 |
Plastic carbon content and DOC accumulation values included for carbon tracking. Missing data for day 56 is due to sample loss during analysis.