Skip to main content
. 2024 Mar 13;124(6):3085–3185. doi: 10.1021/acs.chemrev.3c00581

Table 7. Advances in CNM Fluorescence Sensors for Environmental Monitoring.

  Target Materials System Limit of Detection Ref
Pathogens Polyphenols SWCNTs Soybean and leaf tissue of Tococa spp. (1159)
  E. coli CDs-microspheres Milk 240 CFU/mL (1160)
  E. coli and S. aureus CsWO3-CDs In vitro 70 CFU/mL (1161)
  P. aeruginosa and S. aureus SWCNTs in hydrogel In vitro (1163)
  Acyl-homoserine lactones from Gram-negative bacteria Citric acid and glycine CDs Fish, juice, and milk <7 × 10–5 μM (1164)
  E. coli, S. sciuri, D. desulfuricans, L. monocytogenes, S. aureus, and P. aeruginosa Boronic acid, polymixin, and vancomycin functionalized CDs In vitro (1165)
  E. coli and S. aureus Ag-CDs River water 0.1 mg/mL (1166)
  S. aureus Fe3O4-CDs Milk and juice 8 CFU/mL (1035)
  P. aeruginosa NiFe2O4-CDs In vitro (1167)
ROS/RNS H2O2 Hemin-aptamer-SWCNTs A. thaliana leaves (1225)
  H2O2, dopamine, riboflavin, ascorbic acid, pH ssDNA-SWCNTs In vitro (1226)
  H2O2 SWCNTs Lettuce, arugula, spinach, strawberry blite, sorrel, and A. thaliana leaves (1227)
  H2O2/NO SWCNTs A.thaliana leaves (1228)
  ClO N-CDs Pool and tap water 0.03 μM (1229)
Plant hormones Gibberellins SWCNTs Arabidopsis, lettuce, and basil roots GA3 (542 nM) and GA4 (2.96 μM) (1220)
  Zeatin Dye-labeled aptamers-GO Plant tissue culture 60 nM (1221)
  Jasmonic acid NCQDs@Co metal organic frameworks, molecularly imprinted polymers Rice leaves 0.35 ng/mL (1222)
  Abscisic acid CQDs@ZIF-8/Apt-AuNPs Rice seeds 30.0 ng/mL (1246)
  NAA (1-naphthalene acetic acid) and 2,4-D (2,4-dichlorophenoxyacetic acid) Cationic polymer wrapped-SWCNTs Spinach, A. thaliana, bok choy, and rice NAA (8.2 μM) and 2,4-D (0.35 μM) (1224)
Contaminants and explosives TNP CD+wood In vitro 0.27 μM (1168)
  Picric acid S-CDs In vitro 3.2 μM (1169)
  Picric acid N-CDs Industrial effluent water 1.8 nM (1170)
  TNT N-CDs Sandy soil 30.0 nM (1171)
  Hg2+ and thiophanate methyl Thioctic acid-CDs Tap water, grape juice, and Citri Reticulatae Pericarpium water Hg2+ (33.3 nM) and TM (7.6 nM) (1172)
  Malathion Au-CDs Entire cabbage 1 nM (1173)
  Methyl orange, rhodamine 6G, and bromophenol blue N-Oxidized CDs In vitro 38 nM (1174)
  Carbendazim Serine and histidine functionalized GQDs Tomatoes 6.1 × 10–17 M (1175)
  Pyrene GO-GQDs Lake water 0.325 μM (1176)
  Tetracycline hydrochloride Poly(diallyldimethylammonium) chloride functionalized graphene Milk 0.9284 nM (1177)
  TNP CDs Lake and tap water 1.31 μM (tap water) and 0.99 μM (lake water) (1178)
  Tetracycline Alginate-CDs In vitro 2 μM (1179)
  PNP (4-nitrophenol), DNP (1,3-dinitrophenol), TNP (1,3,5-trinitrophenol), MET (metronidazole), DCNA (2,6-dichloro-4-nitroaniline) NiFe2O4-CDs River water PNP: 65 nM (1180)
      DNP: 74 nM  
      TNP: 78 nM  
      MET: 57 nM  
      DCNA: 100 nM  
  TNP ZnSe-CDs River water 12.4 μM (1181)
  F Pyrene-boronic acid-based CDs In vitro 0.59 μM (1182)
  Glyphosate N-CDs@SiO2 Malt 3.4 ng/mL (1183)
  Methotrexate N,S-CDs In vitro 12 ng/mL (1184)
  Malaoxon GO sheet Agricultural surplus water, carrot, and grape juice 1 nM (1185)
Metals As3+ SWCNTs Spinach, Cretan brake fern, and indica rice 0.6 and 0.2 ppb of As after 7 and 14 d (1186)
  Ag+ N-CDs Lake water 0.5 nM (1187)
  Cr6+ Chitosan-based hydrogel/titanate/cellulose nanofibers-CDs In vitro 8.5 mg/L (1188)
  Hg2+ Eu-CDs Drinking water and milk 0.2 nM (1189)
  Pb2+ Thiolated-CDs Onion cell walls (1190)
  Fe3+ CDs In vitro 355 nM (1191)
  Hg2+, Pb2+, and Cu2+ CDs Pearl river water Hg2+ (5.8 nM), Pb2+ (0.12 μM), and Cu2+ (0.076 μM) (1192)
  Cr6+ EDTA-CDs River water 0.8 μM (1193)
  Fe2+ CDs In vitro 0.62 ppm (1194)
  Cr6+ Benzalkonium chloride-CDs Tap water 0.03 μM (1195)
  Cu2+ N,S-CDs Tap water 0.3 μg/mL (1196)
  Pb2+ CDs In vitro 58.63 μM (1197)
  Hg2+ and Pb2+ Nanofiber/Fe-CDs In vitro (1198)
  Co2+, Fe3+, Hg2+, and Pb2+ CDs In vitro Co2+ (96.8 nM), Fe3+ (61.7 nM), Hg2+ (39.5 nM), and Pb2+ (37.1 nM) (1199)
  Pb2+ and Cu2+ AuCNs/N-CDs River water Pb2+ (0.5 μM) and Cu2+ (0.15 μM) (1200)
  Hg2+ CDs River water 1.26 ng/mL (1201)
  Pb2+, Cu2+, and Ni2+ CDs In vitro Pb2+ (0.01 μM), Cu2+ (0.1 μM), and Ni2+ (0.1 μM) (1202)
  Cu2+ CDs In vitro 10 nM (1203)
  Cr3+ and Pb2+ CDs River water Cr3+ (27 nM) and Pb2+ (34 nM) (1204)
  Pb2+ and Hg2+ CDs River water Pb2+ (0.14 nM) and Hg2+ (0.22 nM) (1205)
  Fe3+ CDs In vitro 18 mg/L (1206)
  Hg2+ N-CDs Seafood 37 nM (1207)
  Ag+ CDs River water 1.4 nM (1208)
  Hg2+ Graphitic carbon nitride quantum dots Tap and rainwater (1209)
  Fe3+, Cu2+, and Hg2+ N-GQDs Tap water Fe3+ (66.7 nM), Cu2+ (146.5 nM), and Hg2+ (47.9 nM) (1210)
  Hg2+ and Fe3+ N-GQDs Drinking water 0.1 μM (1211)
  Hg2+ and F B,N-GQDs In vitro Hg2+ (0.16 μM) and F (0.18 mM) (1212)
  Hg2+ B,N-GQDs River water 6.4 nM (1213)
  Fe3+ B-GQDs River water 31.2 nM (1214)
  Hg2+, Pb2+, Cr2+, and Mn2+ SWCNTs Fish tissue extract 33 nM for Hg2+ (1264)
  Cu2+, Cd 2+, Hg2+, and Pb2+ DNA-wrapped SWCNTs In vitro 100 μM (1265)
VOC (volatile organic compounds) Diisopropylamine (DIPA) and dioxane Carbon nano-onion (CNO) In vitro 200 nM (1216)
  Acetone CDs In vitro 1.5% v/v of acetone to water (1217)
  Cr(VI), nitrobenzene (NB), m-nitroaniline (m-NA), and p-nitroaniline (p-NA) MO-CNTs In vitro Cr(VI) (19 nM), NB (2 nM), m-NA (2 nM), and p-NA (2 nM) (1218)
  Chloroform CDs In vitro 3 ppb (1219)