Table 2. Parameters Related to the Basic Physical Properties of the Different Glasses along with Cation Radii, r, Based on Shannon14 for Eightfold-Coordinated Ba2+ Ions24 and Sixfold-Coordinated Ln3+ Ions,25,26 and the Corresponding Calculated Field Strengths.
| parameter | glass | |||
|---|---|---|---|---|
| Ba | Nd | Gd | Yb | |
| density, ρ (g/cm3) | 3.700 | 3.780 | 3.826 | 3.794 |
| average molar mass, Mav (g/mol) | 147.64 | 154.96 | 156.00 | 157.27 |
| molar volume, Vm (cm3/mol) | 39.90 | 40.99 | 40.77 | 41.45 |
| Ln3+ concentration, N (× 1020 ions/cm3) | 11.75 | 11.82 | 11.62 | |
| Ln3+–Ln3+ mean distance, d (Å) | 9.48 | 9.46 | 9.51 | |
| [O]/[P] | 3.00 | 3.08 | 3.08 | 3.08 |
| cation radius,ar (Å) | 1.42 | 0.983 | 0.938 | 0.868 |
| cation field strength, F = Z/r2 (Å–2) | 0.992 | 3.105 | 3.410 | 3.982 |
From Shannon.14