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. 2024 Mar 18;128(12):2995–3003. doi: 10.1021/acs.jpcb.3c07767

Table 2. Parameters Related to the Basic Physical Properties of the Different Glasses along with Cation Radii, r, Based on Shannon14 for Eightfold-Coordinated Ba2+ Ions24 and Sixfold-Coordinated Ln3+ Ions,25,26 and the Corresponding Calculated Field Strengths.

parameter glass
Ba Nd Gd Yb
density, ρ (g/cm3) 3.700 3.780 3.826 3.794
average molar mass, Mav (g/mol) 147.64 154.96 156.00 157.27
molar volume, Vm (cm3/mol) 39.90 40.99 40.77 41.45
Ln3+ concentration, N (× 1020 ions/cm3)   11.75 11.82 11.62
Ln3+–Ln3+ mean distance, d (Å)   9.48 9.46 9.51
[O]/[P] 3.00 3.08 3.08 3.08
cation radius,ar (Å) 1.42 0.983 0.938 0.868
cation field strength, F = Z/r2–2) 0.992 3.105 3.410 3.982
a

From Shannon.14