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. 2024 Apr 2;14:7809. doi: 10.1038/s41598-024-57412-4

Table 2.

Kinetic parameters of NRPA in the adsorption of CR.

Co (mg L−1) 25 50 75 100 125 150 175 200
Pseudo-first order Qe exp (mg g−1) 9.270 16.680 28.650 45.780 58.930 73.440 98.530 103.470
Qe cal (mg g−1) 10.260 15.830 29.030 44.530 57.170 74.210 97.250 104.360
k1 (min−1) 0.418 0.542 0.570 0.651 0.752 0.836 0.854 0.888
R2 0.997 0.998 0.995 0.987 0.998 0.988 0.998 0.996
%SSE 0.032 0.015 0.004 0.008 0.009 0.003 0.004 0.003
RMSE 0.096 0.115 0.117 0.126 0.128 0.462 0.573 0.588
Pseudo-second order Qe cal (mg g−1) 13.838 20.600 32.720 50.734 62.076 87.680 96.540 115.103
k2 (g mg−1 min−1) 0.204 0.299 0.347 0.364 0.588 0.576 0.747 0.763
R2 0.896 0.922 0.889 0.936 0.975 0.967 0.878 0.983
%SSE 0.149 0.071 0.043 0.033 0.016 0.058 0.006 0.034
RMSE 0.106 0.122 0.145 0.179 1.433 1.723 2.331 2.127
Elovich α (mg (g min)−1) 0.166 0.196 0.254 0.772 0.939 1.208 1.475 1.643
β (g mg−1) 0.115 0.172 0.208 0.278 0.569 0.643 0.669 0.865
R2 0.988 0.986 0.989 0.996 0.996 0.988 0.991 0.997
Intra-particle diffusion K1d (mg g−1 min−0.5) 0.219 0.370 0.558 0.763 1.454 1.705 2.359 4.563
C1(mg g−1) − 0.356 − 0.400 − 0.872 − 1.290 1.258 2.290 5.875 7.358
R2 0.984 0.955 0.978 0.947 0.988 0.976 0.987 0.995