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α-Tertiary amine scope for the zinc-mediated carbonyl alkylative amination reaction. aAmine hydrochloride salt. bCopper iodide (50 mol %), ketone (2.5 equiv), alkyl halide (4 equiv), DCM/HFIP (5:1, 0.67 M). cZinc (8 equiv), alkyl halide (5 equiv).
