Table 2.

Scope of the alkene partner for the intermolecular aminoarylation with arylsulfinylamide (S_S)-1

Unless otherwise noted, reactions were carried out under the standard conditions. Full conversion of the starting material was observed, and yields are reported after purification by column chromatography in silica gel. All compounds were obtained with >20:1 d.r. The d.r. and e.r. values were determined by ¹H NMR of the crude reaction mixture and by chiral stationary HPLC of the isolated products, respectively.

^a5 mol% of [Ir[(dFCF₃)ppy]₂(dtbpy)]PF₆] at 0 °C. n-Bu, n-butyl.