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. Author manuscript; available in PMC: 2025 Mar 20.
Published in final edited form as: J Am Chem Soc. 2024 Mar 7;146(11):7165–7172. doi: 10.1021/jacs.4c00564

Figure 1.

Figure 1.

Characterization of alkali metal-isothiourea-boronate catalyst structures by (A) single-crystal X-ray diffraction; (B) IR spectroscopy; and (C) NMR studies. Hydrogen atoms and close contacts in the crystal structure of K-3f·THF are omitted for clarity. (D) Electrostatic potential map of anion derived from deprotonation of 3f. Red = electron-rich, blue = electron-poor. (E) Proposed model of catalyst structure-enantioselectivity relationship.