Table 1.
The catalytic performance for the chemical conversion of CO2 catalyzed by various catalytic systems using propylene oxide (PO) as a model substrate.
| Entry | Polymeric material | BET [m2g−1] | CO2 uptake [wt.%] | t [h] | T [°C] | P CO2 [MPa] | Yield [%] | no. of runs | TOF [h−1] | TON | References |
|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | Co‐CMP a) | 965 | 7.93 c) |
48 1 |
25 100 |
0.1 3 |
82 98 |
22 1 |
3.5 201 |
167 201 |
[9] |
| 2 | Al‐CMP a) | 798 | 7.65 c) |
48 1 |
25 100 |
0.1 3 |
78 91 |
3 1 |
3.3 187 |
160 187 |
|
| 3 | Zn‐CMP a) | 791 | 5.84 c) |
48 1 |
25 120 |
0.1 3 |
76 94 |
10 1 |
8.0 470 |
384 470 |
[64] |
| 4 | Cr‐CMP a) | 738 | 7.17 c) |
48 1 |
25 100 |
0.1 3 |
68 99 |
10 1 |
3.2 224 |
154 224 |
[74] |
| 5 | Zn@SBMMP a) | 423 | 9.40 d) | 4 | 80 | 2 | 95 | 1 | 50.8 | 203 | [75] |
| 6 | Al‐CMP b) | 839 | 2.74 c) 4.30 d) |
5 5 |
70 100 |
3 3 |
74 91 |
5 1 |
296.0 364 |
1480 1820 |
[76] |
| 7 | PCP‐Cl | 755 | 6.14 c) 10.17 d) | 12 | 100 | 3 | 99 | 4 | n.r. | n.r. | [77] |
| 8 | HUST‐1‐Co a) | 1360 | 13.17 c) 21.39 d) | 30 | 25 | 0.1 | 95 | 15 | 103.0 | 3101 | [78] |
| 9 | Co@PDVB‐VP‐0.5 a) | 479 |
6.51 c) 8.10 d) |
48 0.75 |
30 100 |
1 e) 1 e) |
99 99 |
5 1 |
16.2 1034.3 |
778 776 |
[79] |
| 10 | Co‐CMP‐2 a) | 475 | 6.46 c) | 1 | 100 | 3 | 99 | 10 | 236.0 | 236 | [80] |
| 11 | Al‐iPOP‐1 | 52 | 5.80 d) | 3 | 40 | 1 | 97 | 6 | 892.0 | 2676 | [81] |
| 12 | Al‐iPOP‐`2 | 86 | 6.60 d) | 99 | 6 | 916.0 | 2748 | ||||
| 13 | POF‐PNA‐Br− | 288 | n.r. |
48 8 |
40 60 |
0.1 1 |
98 >99 |
3 1 |
7.0 42.6 |
337 341 |
[82] |
| 14 | IPF‐CSU‐1 a) | n.r. | n.r. | 48 | 25 | 0.1 | 99 | 3 | n.r. | n.r. | [83] |
| 15 | p‐TBIB a) | 840 | 12.31 c) 19.79 d) | 24 | 25 | 0.1 | 97 | 10 | 9.9 | 237 | [72] |
| 16 | CPBr‐2 | 370 | 8.81 d) | 7 | 90 | 2.5 | 95 | 5 | n.r. | n.r. | [84] |
| 17 | SCHPP‐3 a) | 518 | 5.77 d) | 5 | 120 | 2 | 93 | 1 | n.r. | n.r. | [71] |
| 18 | DTBBQ‐CMP a) | 16 | n.r. | 48 | 25 | 0.1 | 99 | 5 | 60.5 | 2903 | [85] |
| 19 | Zn‐salen‐CMP a) | 589 | 4.15 c) 6.58 d) | 1.5 | 120 | 3 | 92 | 8 | 307.0 | 461 | [70] |
| 20 | HMP‐TAPA a) | 424 | 10.67 d) | 6 | 80 | 0.6 | >99 | 1 | 78.7 | 472 | [68] |
| 21 | TBB‐BPY‐Co a) | 1279 | 8.19 c) 15.73 d) | 48 | 25 | 1 | 85 | 10 | 306.0 | 14 680 | [86] |
| 22 | CMP‐Salen‐Zn a) | 444.6 | 4.04 c) 5.95 d) | 12 | 120 | 0.1 | 99 | 1 | n.r. | n.r. | [87] |
| 23 | Co‐Por‐POP‐2 a) | 780 |
9.83 c) 15.10 d) |
48 48 |
25 25 |
0.1 1 |
73 89 |
10 1 |
20.8 25.6 |
997 1227 |
[88] |
| 24 | Al‐Por‐POP‐2 a) | 1037 | 10.31 c) 17.12 d) |
48 1 |
25 100 |
0.1 3 |
95 99 |
10 1 |
65.5 3261.0 |
3142 3261 |
[10] |
| 25 | HVPOP‐Br | 266.7 |
≈4.1 c) ≈6.5 d) |
12 | 120 | 1 | 93 | 1 | n.r. | n.r. | [89] |
a)
TBAB co‐catalyst;
b)
PPNCl co‐catalyst (see Figure 1);
c)
298 K;
d)
273 K; n.r. = not reported; TOF = Turnover frequency; TON = Turnover number; t = reaction time; T = reaction temperature; P = reaction pressure;
e)
CO2:N2 at 0.15:0.85.