Table 3.

Non‐epoxide routes and yields for the chemical conversion of CO₂ catalyzed by CMPs.

Entry	Route of conversion	Polymeric material	BET [m2g−1]	CO2 uptake [wt%]	t [h]	T [°C]	P CO2 [MPa]	Yield [%]	References
1	A. Carboxylation of alkynes	CMP‐Cu	–	–	60	25	0.1	31.2	[12]
2		MOP‐PZ−Ag	897.5	11.55 a) 18.37 b)	24	50	0.1	92	[102]
3		Ag@NPOP‐1 Ag@NPOP‐2	–	–	12	60	0.1	94 92.1	[103]
4	B1. Carboxylative cyclization of propargyl amines	Ag@NPOP‐1 Ag@NPOP‐2	–	–	2	50	0.1	97 93	[103]
5	B2. Carboxylative cyclization of propargyl alcohols	Ag@UCPP	102	2.65 a) 2.92 b)	24	25	1	99	[104]
6		F‐MOP‐3‐Ag	399	6.3 b)	10	25	1	100	[105]
7	C. Methylation of amines	Azo‐MOP‐3‐Ru	370	8.21 b)	24	120	0.5	99	[13]
8	D. Formylation of amines	CarPy‐CMP@Ru	735	9 a) 17.1 b)	24	130	4	91	[11]
9	E. Hydrosilylation	CMP‐NHC‐CuCl	388	–	10	20	0.1	91.7	[101]

^a) 298 K;

^b) 273 K