Table 1. Molecular Parameters of LAL Triblock Copolymers^a.

sample	middle block					triblock			G (kPa)	tensile fracture strain	SAXS
	nHA	nAAPA	ntot	λ	D̵	nBnMA	fBnMA (%)	D̵			q* (nm–1)	d (nm)
TR1	251	0	251	0	1.26	30	10.4	1.28	2.52	1.22 ± 0.02	0.172	36.5
TR2	239	23	262	0.09	1.19	36	11.5	1.23	4.07	1.39 ± 0.05	0.171	36.7
TR3	180	60	240	0.25	1.22	32	10.8	1.26	10.55	1.57 ± 0.05	0.194	32.4
TV1	180	60	240	0.25	1.22	40	13.2	1.28	12.14	1.60 ± 0.17	0.218	28.8
TV2	188	62	250	0.25	1.22	102	27.3	1.35	67.25	0.95 ± 0.15	0.160	39.2
TV3	188	62	250	0.25	1.22	132	32.7	1.33	2730.00	0.82 ± 0.06	0.168	37.4

^an_HA, number of HA repeating units per middle block; n_AAPA, number of AAPA repeating units per middle block; n_tot, total number of repeating units per middle block; n_BnMA, number of BnMA repeating units for each end linear PBnMA blocks; λ, fraction of AAPA repeating units per middle block; f_BnMA, volume fraction of PBnMA end blocks; D̵, polydispersity index (PDI); G, shear storage modulus G′ at 0.1 rad/s; q*, wavenumber of the primary scattering peak; d = 2π/q*, average center-to-center distance between two neighboring glassy domains; TR: triblock copolymers with different fractions of reversible bonds; TV: triblock copolymers with various volume fractions of end blocks. Error: standard deviation for n ≥ 3.