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. 2024 Mar 22;17(7):1460. doi: 10.3390/ma17071460

Table 3.

Hydrolysis process of polymers.

Polymer/Feedstock Type Operating Conditions Products Ref.
PET Acid hydrolysis Depolymerization of PET occurs at 100 °C in 96 h and may add catalysts, such as MSO4 Terephthalic acid (TPA) and ethylene glycol (EG) [41]
PET Alkaline hydrolysis Carried out in an alkaline solution of NaOH or KOH with a concentration range of 4–20 wt%, with the reaction taking 3–5 h at 210–250 °C Ethylene glycol (EG) and terephthalic salts [42]
PET Transesterification (methanol) Depolymerized at 65 °C in a stirred reactor, catalyzed using Na2CO3 and a MeOH/EG molar ratio > 15 for 90 min DMT + EG [43]
Polylactic acid (PLA) Hydrolysis Carried out at a temperature of 60–80 °C and takes 15–50 days Lactic acid [44]
Nylon polymers (nylon 6, nylon 6/6, nylon 12, and nylon 6/12) Acid hydrolysis Carried out at 350 °C for 10 min ϵ-caprolactam [45]