No. | 1 | 2 | 3 | 4 | ||||
---|---|---|---|---|---|---|---|---|
δ C | δ H (mult., J in Hz) | δ C | δ H (mult., J in Hz) | δ C | δ H (mult., J in Hz) | δ C | δ H (mult., J in Hz) | |
1 | 39.8 | 0.97 (m)/1.63 (m) | 39.7 | 0.97 (m)/1.63 (m) | 39.7 | 0.97 (m)/1.62 (m) | 39.7 | 0.96 (m)/1.62 (m) |
2 | 27.0 | 1.70(m)/1.86 (m) | 27.0 | 1.70(m)/1.85 (m) | 26.9 | 1.70(m)/185 (m) | 27.0 | 1.70(m)/1.85 (m) |
3 | 90.8 | 3.12 (dd, 12.0, 4.2) | 90.8 | 3.13 (dd, 12.0, 4.2) | 90.8 | 3.12 (dd, 12.0, 4.8) | 90.8 | 3.12 (dd, 12.0, 4.2) |
4 | 40.8 | — | 40.7 | — | 40.7 | — | 40.7 | — |
5 | 56.9 | 0.72 (br d, 11.4) | 57.5 | 0.76 (br d, 11.4) | 57.0 | 0.75 (br d, 11.4) | 57.0 | 0.75 (br d, 12.0) |
6 | 19.3 | 1.37 (m)/(1.49) | 19.3 | 1.37 (m)/1.50 (m) | 19.3 | 1.37 (m)/1.50 (m) | 19.3 | 1.35 (m)/1.48 (m) |
7 | 33.9 | 1.29 (m)/1.48 (m) | 33.9 | 1.30 (m)/1.48 (m) | 33.9 | 1.30 (m)/1.48 (m) | 33.9 | 1.29 (m)/1.46 (m) |
8 | 40.1 | — | 40.1 | — | 40.1 | — | 40.1 | — |
9 | 49.0 | 1.58 (m) | 49.0 | 1.58 (m) | 49.0 | 1.60 (m) | 49.0 | 1.58 (m) |
10 | 37.9 | — | 37.9 | — | 37.9 | — | 37.9 | — |
11 | 24.6 | 1.90–1.92 (m) | 24.6 | 1.90–1.92 (m) | 24.7 | 1.90–1.92 (m) | 24.6 | 1.90–1.92 (m) |
12 | 124.3 | 5.34 (t, 3.0) | 124.2 | 5.31 (t, 3.0) | 124.2 | 5.28 (t, 3.6) | 123.9 | 5.28 (t, 3.6) |
13 | 144.2 | — | 144.0 | — | 144.8 | — | 144.8 | — |
14 | 42.9 | — | 42.9 | — | 42.8 | — | 42.9 | — |
15 | 28.9 | 1.13 (m)/1.80 (m) | 28.9 | 1.10 (m)/1.78 (m) | 29.0 | 1.10 (m)/1.78 (m) | 28.9 | 1.08 (m)/1.77 (m) |
16 | 24.2 | 1.85 (m)/2.17a | 24.1 | 1.77(m)/2.12 (td, 13.2, 3.6) | 24.0 | 1.77(m)/2.07 (td, 13.2, 2.4) | 24.0 | 1.72 (m)/2.05 (td, 13.2, 3.0) |
17 | 48.5 | — | 47.9 | — | 48.4 | — | 48.3 | — |
18 | 48.4 | 2.75 (dd, 13.8, 4.8) | 44.7 | 2.81 (dd, 13.8, 4.2) | 41.4 | 2.90 (dd, 13.2, 4.2) | 41.8 | 2.90 (dd, 13.2, 3.6) |
19 | 42.6 | 2.10 (dd, 13.8, 4.6) 2.57 (t, 13.8) | 47.6 | 1.47a 2.00 (t, 13.8) | 41.4 | 1.11a 1.83 (t, 13.8) | 41.4 | 1.12a 1.83 (t, 13.4) |
20 | 149.6 | — | 71.3 | — | 36.8 | — | 36.8 | — |
21 | 30.9 | 2.15a 2.24 (td, 13.2, 3.6) | 35.6 | 1.51 (m)/1.65 (m) | 29.5 | 1.18 (m)/1.52 (m) | 29.3 | 1.18 (m)/1.50 (m) |
22 | 38.5 | 1.55 (m)/1.91 (m) | 39.8 | 1.67 (m)/1.75 (m) | 32.6 | 1.65 (m)/1.74 (m) | 32.6 | 1.65 (m)/1.74 (m) |
23 | 28.5 | 0.95 (s) | 28.5 | 0.93 (s) | 28.5 | 0.93 (s) | 28.5 | 0.93 (s) |
24 | 16.9 | 0.73 (s) | 16.9 | 0.73 (s) | 16.9 | 0.72 (s) | 16.9 | 0.72 (s) |
25 | 16.1 | 0.95 (s) | 16.0 | 0.95 (s) | 16.0 | 0.93 (s) | 16.0 | 0.94 (s) |
26 | 17.8 | 0.80 (s) | 18.0 | 0.80 (s) | 17.8 | 0.79 (s) | 17.8 | 0.79 (s) |
27 | 26.3 | 1.18 (s) | 26.2 | 1.18 (s) | 26.3 | 1.17 (s) | 26.3 | 1.17 (s) |
28 | 177.3 | — | 177.6 | — | 178.0 | — | 178.0 | — |
29 | — | — | — | — | 74.2 | 3.21 (s) | 74.3 | 3.21 (s) |
30 | 107.5 | 4.64 (br s) 4.65 (br s) | 25.0 | 1.25 (s) | 19.7 | 0.95 (s) | 19.7 | 0.95 (s) |
Overlapped signal.