Rate coefficients and Arrhenius parameters of 3M13PD, 14HD, and 12PD reaction with OH at temperatures of 273–318 K.
| Diene | T (K) | k × 10−11 cm3 per molecule per s | A × 10−12 cm3 per molecule per s | −Ea/R (K) | R 2 |
|---|---|---|---|---|---|
| 3M13PD | 273 | 15.01 ± 1.25 | 80.98 ± 22.30 | 173 ± 71 | 0.82 |
| 288 | 14.86 ± 1.22 | ||||
| 297a | 13.90 ± 0.80 | ||||
| 298 | 15.09 ± 0.72 | ||||
| 308 | 13.96 ± 1.19 | ||||
| 318 | 13.78 ± 1.18 | ||||
| 14HD | 273 | 11.74 ± 1.09 | 9.82 ± 5.1 | 666 ± 123 | 0.88 |
| 283 | 9.78 ± 0.99 | ||||
| 288 | 9.67 ± 0.99 | ||||
| 297a | 9.25 ± 0.55 | ||||
| 298 | 9.13 ± 0.62 | ||||
| 308 | 9.17 ± 0.96 | ||||
| 318 | 7.73 ± 0.88 | ||||
| 12PD | 273 | 4.96 ± 0.73 | 1.13 ± 0.87 | 1038 ± 167 | 0.90 |
| 283 | 4.81 ± 0.70 | ||||
| 288 | 4.24 ± 0.66 | ||||
| 297a | 3.63 ± 0.13 | ||||
| 298 | 3.34 ± 0.40 | ||||
| 308 | 3.23 ± 0.57 | ||||
| 318 | 3.12 ± 0.56 |
Cite from Ohta, T. (1983).39