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. 2024 Apr 16;14(18):12303–12312. doi: 10.1039/d3ra08750f

Rate coefficients and Arrhenius parameters of 3M13PD, 14HD, and 12PD reaction with OH at temperatures of 273–318 K.

Diene T (K) k × 10−11 cm3 per molecule per s A × 10−12 cm3 per molecule per s Ea/R (K) R 2
3M13PD 273 15.01 ± 1.25 80.98 ± 22.30 173 ± 71 0.82
288 14.86 ± 1.22
297a 13.90 ± 0.80
298 15.09 ± 0.72
308 13.96 ± 1.19
318 13.78 ± 1.18
14HD 273 11.74 ± 1.09 9.82 ± 5.1 666 ± 123 0.88
283 9.78 ± 0.99
288 9.67 ± 0.99
297a 9.25 ± 0.55
298 9.13 ± 0.62
308 9.17 ± 0.96
318 7.73 ± 0.88
12PD 273 4.96 ± 0.73 1.13 ± 0.87 1038 ± 167 0.90
283 4.81 ± 0.70
288 4.24 ± 0.66
297a 3.63 ± 0.13
298 3.34 ± 0.40
308 3.23 ± 0.57
318 3.12 ± 0.56
a

Cite from Ohta, T. (1983).39