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ACP-dependent dehydrogenation involved in the biosynthesis of NFAT-133 and its analogues. (a) Chemical structures of NFAT-133 and its analogues; (b) A variant of acyl-CoA dehydrogenase, NftN, may catalyze the conversion of 2-pentenoyl-ACP to 2,4-pentadienoyl-ACP during NFAT-133 polyketide assembly.
