Table 3. Selectivity of the Carbon-Based Gas Products, and the Coverage of the Surface Species over the Rh(111) Surface under Various Reaction Conditionsa.
T = 473.15 K, PH2 = 0.75 bar, PCO2 = 0.25 bar | T = 473.15 K, PH2 = 0.8 bar, PCO2 = 0.2 bar | T = 473.15 K, PH2 = 0.9 bar, PCO2 = 0.1 bar | |
---|---|---|---|
CH4 selectivity | 0.654 | 0.759 | 0.882 |
HCOOH selectivity | 0.346 | 0.241 | 0.118 |
θCO | 0.410 | 0.319 | 0.180 |
θCO2 | 0.021 | 0.009 | 0.006 |
θCOOH | 0.001 | 0.007 | 0.004 |
θHCOO | 0.009 | 0.005 | 0.004 |
θO | 0.004 | 0.004 | 0.001 |
θH (hollow) | 0.129 | 0.210 | 0.348 |
θOH | 0.001 | 0.002 | 0.001 |
θH2O | 0.047 | 0.026 | 0.014 |
θH (top) | 0.367 | 0.417 | 0.440 |
Coverage is defined as earlier mentioned.