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. 2024 Apr 23;15:3434. doi: 10.1038/s41467-024-47426-x

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© The Author(s) 2024

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 5 — a Illustration of peptide hydrolysis using HD-US-UiO-66, (b) Pseudo first order hydrolysis rate of glycylglycine (GG) to glycine (G) using HD-US-UiO-66-NH₂ and MI-US-UiO-66-NH₂ nanoMOFs, reference refers to the value reported in the previous studies under the same conditions⁴⁷, (c) Selectivity of hydrolysis by HD-US-UiO-66-NH₂ and HD-200-UiO-66-NH₂ in producing the desired product G, as the starting concentration of GG increases from 2 mM to 500 mM, (d) Recyclability of HD-US-UiO-66-NH₂ over 5 reaction cycles in comparison to best-performing MOFs to date, percentage compared to yield of cycle 1, (e) illustration of amide bond condensation using HD-US-UiO-66, in MeOH, (f) Amide bond formation yield with HD-US-UiO-66 and HD-US-UiO-66-NH₂ starting from G, GG, and AG.