Table 2.
Luteolin-7--o-glucuronide |
Vernoamyoside D |
Vernotolaside |
||||||
---|---|---|---|---|---|---|---|---|
C/H Atom |
13C (ppm) | 1H (ppm) | C/H Atom |
13C (ppm) | 1H (ppm) | C/H Atom |
13C (ppm) | 1H (ppm) |
2 | 171.1 | ___ | 1 | 35.2 | 1.2(d) | 1 | 102.31 | 3.40 |
3 | 104.0 | 6.4(s) | 2 | 28.3 | 2.4(d) | 2 | 63.31 | 1.07 |
4 | 172.9 | ___ | 3 | 72.4 | 3.5(s) | 3 | 82.08 | ____ |
5 | 160.2 | 8.1(s) | 4 | 34.5 | 5.3(s) | 4 | 97.16 | ____ |
6 | 99.5 | 6.2 (brs) | 5 | 38.6 | 1.6(s) | 5 | 60.66 | 2.42 |
7 | 170.2 | ___ | 6 | 29.7 | 3.4(d) | 6 | 70.65 | 3.70 |
8 | 90.3 | 6.2 (brs) | 7 | 57.3 | 7.3(s) | 7 | 56.70 | ___ |
9 | 152.4 | ___ | 8 | 60.4 | __ | 8 | 75.60 | 0.97 |
10 | 99.6 | ___ | 9 | 80.3 | __ | 9 | 56.70 | 0.85 |
1’ | 120.2 | ___ | 10 | 62.4 | __ | 10 | 78.42 | 3.68 |
2’ | 110.3 | 7.3(S) | 11 | 40.3 | 3.4 | sugar | ||
3’ | 145.6 | 8.2 (brs) | 12 | 36.2 | 5.5(d) | 1′ | 48.13 | 3.40 |
4’ | 150.0 | 7.4 (brs) | 13 | 39.1 | 1.9(d) | 2′ | 38.40 | 3.20 |
5’ | 115.9 | 6.8(s) | 14 | 38.3 | 2.1(m) | 3′ | 40.31 | 3.37 |
6’ | 119.2 | 7.4(s) | 15 | 56.2 | 2.5 | 4′ | 36.76 | 3.10 |
Sugar | 16 | 56.3 | 1.9 | 5′ | 39.50 | 3.38 | ||
1″ | 99.0 | 5.2(s) | 17 | 44.2 | 1.4 | 6′ | 44.26 | 3.56 |
2″ | 70.0 | 5.1(s) | 18 | 56.8 | 2.2 | _ | ___ | ___ |
3″ | 72.0 | 5.3(s) | 19 | 70.4 | 0.8(s) | _ | ___ | ___ |
4″ | 65.0 | 5.2(s) | 20 | 76.4 | 0.6(s) | _ | ___ | ___ |
5″ | 63.0 | 5.2(s) | 21 | 60.4 | ___ | _ | ___ | ___ |
6″ | nil | ___ | 22 | 38.2 | ___ | _ | ___ | ___ |
23 | 45.1 | 7.4 (brs) _ | _ | ___ | ___ | |||
_ | _ | ___ | 24 | 50.4 | 5.2(m) | _ | ___ | ___ |
_ | _ | ___ | 25 | 70.3 | 2.1(m) | _ | ___ | ___ |
_ | _ | ___ | 26 | 40.4 | 0.8(d) | _ | ___ | ___ |
_ | _ | ___ | 27 | 38.3 | 0.9(d) | _ | ___ | ___ |
_ | _ | ___ | 28 | 29.4 | ___ | _ | ___ | ___ |
_ | _ | ___ | 29 | 44.0 | 2.0(s) | _ | ___ | ___ |
_ | _ | ___ | Sugar | |||||
_ | _ | ___ | 1′ | 74.5 | 4.1(d) | _ | ___ | ___ |
_ | _ | ___ | 2′ | 79.0 | 2.8 | _ | ___ | ___ |
_ | _ | ___ | 3′ | 72.0 | 3.1 | _ | ___ | ___ |
_ | _ | ___ | 4′ | 77.3 | 3.0 | _ | ___ | ___ |
_ | _ | ___ | 5′ | 64.1 | 3.2 | _ | ___ | ___ |
_ | _ | ___ | 6′ | 58.3 | 3.4 | _ | ___ | ___ |