TABLE 2.
1H and 13C chemical shifts observed for micrococcin P1 in CD3OH at 318 K
No.a | Chemical shift (ppm)
|
No.a | Chemical shift (ppm)
|
|||
---|---|---|---|---|---|---|
δ(1H) | δ(13C) | δ(1H) | δ(13C) | |||
1 | 1.19 | 20.6 | 28 | 1.55 | 20.8 | |
2 | 3.95 | 67.5 | 29 | 170.9 | ||
3 | 3.37, 3.25 | 48.3 | 30 | 9.53 | ||
4 | 7.91 | 31 | 130.6 | |||
5 | 167.4 | 32 | 6.57 | 130.9 | ||
6 | 131.2 | 33 | 1.86 | 14.1 | ||
7 | 6.73 | 131.8 | 34 | 168.0 | ||
8 | 1.85 | 13.7 | 35 | 8.10 | 125.1 | |
9 | 9.57 | 36 | 149.7 | |||
10 | 162.1 | 37 | 162.5 | |||
11 | 151.1 | 38 | 8.48 | |||
12 | 8.32 | 126.3 | 39 | 5.24 | 57.4 | |
13 | 163.9 | 40 | 2.61 | 34.4 | ||
14 | 150.9 | 41 | 1.14 | 19.2 | ||
15 | 8.33 | 122.1 | 42 | 1.00 | 20.0 | |
16 | 169.9 | 43 | 171.5 | |||
17 | 151.6 | 44 | 8.26 | 125.6 | ||
18 | 8.32 | 119.9 | 45 | 150.4 | ||
19 | 8.28 | 141.1 | 46 | 163.1 | ||
20 | 129.9 | 47 | 8.50 | |||
21 | 166.1 | 48 | 5.26 | 57.5 | ||
22 | 8.20 | 126.2 | 49 | 4.31 | 69.2 | |
23 | 151.0 | 50 | 1.18 | 20.5 | ||
24 | 162.5 | 51 | 172.2 | |||
25 | 7.94 | − | 52 | 7.95 | 121.8 | |
26 | 4.79 | 59.3 | 53 | 155.0 | ||
27 | 4.60 | 69.6 | 54 | 152.7 |
Numbers correspond to those presented in Fig. 3.