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. 2024 Jan 30;9(5):1154–1163. doi: 10.1039/d3re00490b

Comparison between power-law parameters obtained via MATLAB facilitated parameter fitting for n-heptane dehydrogenation using the Pt/Al2O3 and SCALMS.

Catalyst E A,eff/kJ mol−1 Order m/−a Order n/−b k 0/c Error/% SSE/−
Pt/Al2O3 68.1 0.68 0.26 6.04 × 105 8.47 0.20
Ga84Pt/Al2O3 69.7 0.68 0.00 8.04 × 105 5.55 0.07
a

Reaction order of n-heptane.

b

Reaction order of hydrogen.

c

molheptane gPt−1 h−1 bar−(n+m).