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. 2024 Apr 18;63(17):7589–7603. doi: 10.1021/acs.inorgchem.3c03791

Table 3. Yields of Auration Following Transmetalation and Total Overall Yield of the Gold Complexes Starting from the Free Ligand.

starting complex auration/% overall yield from ligand/%
2,3-[Hg2] 24 18
2-[Hg] 40 36
2,5-[Hg]/2,5-[Hg2]a 17 10
2,4-[Hg] 6 3.5
3,4-[Hg] 13 5
3,5-[Hg]/3,5-[Hg2]a   0
4-[Hg] 48 8
3-[Hg]/5-[Hg] 20b 17
a

Reaction started with the as-obtained mixture of the mono- and dimercurated complexes.

b

Product obtained is 3,5′-[Au]-Cl.