Table 3. Yields of Auration Following Transmetalation and Total Overall Yield of the Gold Complexes Starting from the Free Ligand.
| starting complex | auration/% | overall yield from ligand/% |
|---|---|---|
| 2,3-[Hg2] | 24 | 18 |
| 2-[Hg] | 40 | 36 |
| 2,5-[Hg]/2,5-[Hg2]a | 17 | 10 |
| 2,4-[Hg] | 6 | 3.5 |
| 3,4-[Hg] | 13 | 5 |
| 3,5-[Hg]/3,5-[Hg2]a | 0 | |
| 4-[Hg] | 48 | 8 |
| 3-[Hg]/5-[Hg] | 20b | 17 |
Reaction started with the as-obtained mixture of the mono- and dimercurated complexes.
Product obtained is 3,5′-[Au]-Cl.