. Author manuscript; available in PMC: 2024 May 1.

Published in final edited form as: Chem Soc Rev. 2019 Mar 4;48(5):1362–1389. doi: 10.1039/c8cs00155c

Table 2.

Summary of porosity and functionality in single-component and permanently porous HOFs (until October 2018)

Types	HOFs	Formula	Void/%	Pore size/Å	S_BET/m² g⁻¹	Functionality	Ref.
DAT derivatives	HOF-1a	$C_{37} H_{32} N_{20}$	42	~8.2	359	$C_{2} H_{2}$ / $C_{2} H_{4}$ (56/3.9)^e	28
	HOF-2a	$C_{36} H_{34} N_{20} O_{2}$	54.3	~4.8	238	Separation of chiral secondary alcohols	138
	HOF-3a	$C_{33} H_{27} N_{15}$	75	b7	165	$C_{2} H_{2}$ / ${CO}_{2}$ (47/21)^e	133
	HOF-4a	$C_{61} H_{48} N_{20}$	42.5	3.8 × 8.1	312	$C_{2} H_{4}$ / $C_{2} H_{6}$ (11/3.6)^e	117
	HOF-5a	$C_{38} H_{32} N_{20}$	41.1	~3.9 × 5.5, × 3.9 × 6.8	1101	${CO}_{2}$ / ${CH}_{4}$ (90/—)^e, ${CO}_{2}$ / $N_{2}$ , and $C_{2} H_{2}$ / ${CH}_{4}$ (102/—)^e	130
	HOF-6a	$C_{56} H_{42} N_{24}$	63.4	~6.4, ~7.5	130	Proton conduction, ${CO}_{2}$ / $N_{2}$	145
	HOF-7a	$C_{56} H_{42} N_{24} OZn$	—	3.2 × 4.7, 4.2 × 6.7	124	${CO}_{2}$ / $N_{2}$ (11/—)^e	131
	HOF-9a	$C_{56} H_{42} N_{24} OZn$	—	3.2 × 4.7, 4.2 × 6.7	124	Py/BTX, ${CO}_{2}$ / $N_{2}$ (40/6)^e	132
	HOF-lOa	$C_{56} H_{42} N_{24} OZn$	55	3.2 × 4.7, 4.2 × 6.7	187	Fluorescence ${Ag}^{+}$ sensing	154
Carboxylic acid	IISERP-HOF1	$C_{21} H_{15} {NO}_{6}$	~34	9.1 × 9.4^a	412	${CO}_{2}$ / $N_{2}$ (65/—)^e	121
	HOF-11		33.2	6.2 × 6.8	687	${CO}_{2}$ / ${CH}_{4}$ , ${CO}_{2}$ / $N_{2}$ (30/2)^e, and $C_{2} H_{2}$ / ${CH}_{4}$ (45/8)^e	123
	Tcpb/H3BTB	$C_{27} H_{18} O_{6}$	38	18.5^c	1095	${CO}_{2}$ and $H_{2}$ adsorption	134
	HOF-BTB			12/16.6^c	955	$C_{2} H_{2}$ / ${CH}_{4}$ (64/8.7)^e, $C_{2} H_{4}$ / ${CH}_{4}$ , and $C_{2} H_{6}$ / ${CH}_{4}$	136
	HOF-TCBP	$C_{40} H_{26} O_{8}$	56	17.8 × 26.3	2066	$C_{3}$ / ${CH}_{4}$ and ${CH}_{4}$ / ${CH}_{4}$	112
	PFC-1/ $H_{4} TBAPy$	$C_{44} H_{26} O_{8}$	—	18 × 23	2122	Chemo-photodynamic therapy	115
	CoTCPp	$C_{72} H_{44} N_{4} O_{12} Co$	~19	4.0 × 6.5	98	Alkylbenzene oxidation	160
	TCF-1	$C_{29} H_{20} O_{8}$	17.3	2.9 × 5.5 to 4.2 × 6.4	—	${CO}_{2}$ , ${CH}_{4}$ , and $C_{6} H_{6}$ adsorption	119
	Tp-1	$C_{60} H_{36} O_{12}$	54	~11, 15.8^a	788	Fluorescence and hydrocarbon	97
	T12–1	$C_{66} H_{36} O_{12}$	41	~11, 4.6 × 15.8^a	557	adsorption
	T18–1	$C_{72} H_{36} O_{12}$	58	~11, 7.1 × 15.8^a	—
	Ex-1	$C_{90} H_{48} O_{12}$	59	~11, 11.4 × 15.8^a	—
	TpMe-1	$C_{72} H_{60} O_{12}$	45.2	6.4	561	Fluorescence	151
	TpF-1	$C_{60} H_{24} F_{12} O_{12}$	50.4	14.5	219
	CPHAT-1a	$C_{72} H_{44} N_{4} O_{12}$	31	6.4	649^b	Fluorescence	98
	CBPHAT-la	$C_{72} H_{44} N_{4} O_{12}$	45	14.5	1288	Fluorescence	99
	PETHOF-1	$C_{62} H_{38} O_{12}$	80	~11^c	1150	${CO}_{2}$ / ${CH}_{4}$ (32.6/10.6)^e	85
	PETHOF-2	$C_{62} H_{38} O_{12}$	49	~11^c	1140	${CO}_{2}$ / ${CH}_{4}$ (43.4/4.2)^e
Azole derivatives	Trispyrazole 1	$C_{33} H_{12} F_{12} N_{6}$	56	16.5	1159	Fluorocarbon and hydrocarbon adsorption	88
	Trispyrazole 16	$C_{30} H_{9} F_{12} N_{9}$	—	18	903	—	103
	Tristetrazole 23	$C_{27} H_{6} F_{12} N_{12}$	—	11.9	222	—
	Trispyrazole 25	$C_{51} H_{12} F_{24} N_{6}$	58.1	26.4	1821	—
	Benzotrisimidazole	$C_{12} H_{3} F_{9} N_{6}$	21.7	2.9 × 4.6	131	$O_{2}$ / $Ar$ , $O_{2}$ / $N_{2}$	137
	FDM-15	$C_{23} H_{14} N_{6}$	—	b11.5	749	p-Xylene/ $C_{8} H_{10}$ , $C_{60}$ capture	139
Amide derivatives	TTBI	$C_{23} H_{14} N_{6} O_{3}$	60	14.5, 3.8 × 5.8	2796	${CO}_{2}$ and $H_{2}$ adsorption	52
	$T2-β$	$C_{23} H_{14} N_{6} O_{3}$	—	—	1665	${CH}_{4}$ storage, $C_{3} H_{8}$ / ${CH}_{4}$	53
	$T2-γ$	$C_{23} H_{14} N_{6} O_{3}$	—	19.9	3425
	$T2-δ$	$C_{23} H_{14} N_{6} O_{3}$	—	—	365
	NPSU-3	$C_{46} H_{60} N_{6} O_{5}$	16.1	10.8	29	Organic dyes adsorption	144
Pyridine derivatives	HOF-8	$C_{24} H_{18} N_{6} O_{3}$	24	4.5 × 6.8	—	${CO}_{2}$ / $N_{2}$ , ${CO}_{2}$ / $H_{2}$ and $C_{6} H_{6}$ adsorption	91
	SOF-1a	$C_{60} H_{36} N_{10}$	34	~7.8	474	${CO}_{2}$ and $C_{2} H_{2}$ adsorption	51
Benzoin	Cyclotetrabenzoin	$C_{32} H_{24} O_{8}$	10	—	42	${CO}_{2}$ and $H_{2}$ adsorption	118
Porous molecular	CB[6]	( $C_{36} H_{36} N_{24} O_{12}$ ) $2 H_{2} O$	14.4	6	210	$C_{2} H_{2}$ adsorption	70
solids	TTP	$C_{18} H_{12} N_{3} O_{6} P_{3}$	25	4.6	240^d 59	${CO}_{2}$ and ${CH}_{4}$ adsorption	58
	CC3	$C_{72} H_{84} N_{12}$	—	5.8, 7.2	624	${CO}_{2}$ , ${CH}_{4}$ and $H_{2}$ adsorption	72
	TBC[4]DHQ	$C_{38} H_{44} O_{6}$	—	2.2, 11.2	230	${CO}_{2}$ adsorption	67

Distance of atom centers including vdW radii.

Estimated by PLATON.

Pore size distribution from 77 K $N_{2}$ .

Langmuir surface area.

The adsorption amount (cm³ g⁻¹) at room temperature and 1 bar is presented in parentheses.