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. 2024 Apr 26;106:106887. doi: 10.1016/j.ultsonch.2024.106887

Table 2.

Analysis of variance for the statistical modeling of TPC, TEAC, and FRAP from cocoa bean shell (CBS) and cocoa pod husk (CPH).

Source TPC
TEAC
FRAP
Sum of squares
F-value
Sum of squares
F-value
Sum of squares
F-value
CBS CPH CBS CPH CBS CPH CBS CPH CBS CPH CBS CPH
Model 111025.4 78677.1 13.06** 30.36*** 0.0478 0.0323 4.36 ns 8.58** 0.1818 0.1464 16.42*** 53.70***
XA 14065.4 1179.80 8.54 2.98 0.0165 0.0001 7.42 0.58 0.0132 0.0017 10.61 9.22
XB 3373.3 370.07 2.04 0.93 0.0014 0.0003 0.63 3.37 0.0014 0.0006 1.18 3.30
XC 40144.0 2560.09 24.38* 6.47 0.0066 0.0002 2.98 1.47 0.0382 0.0019 30.55* 10.23
XAXB 2213.6 252.39 1.34 0.63 0.0004 0.0002 0.19 1.37 0.0029 0.0010 2.37 5.77
XAXC 5203.1 10.77 3.16 0.027 0.0005 0.0018 0.25 16.93 0.0054 0.0000 4.33 0.033
XBXC 400.0 82.77 0.24 0.20 0.0003 0.0000 0.15 0.086 0.0001 0.0000 0.057 0.013
XAXA 4033.2 418.64 2.45 1.05 0.0007 0.0000 0.33 0.092 0.0061 0.0019 4.88 10.14
XBXB 1176.7 340.59 0.71 0.86 0.0007 0.0009 0.31 8.90 0.0042 0.0017 3.41 9.35
XCXC 43127.8 74214.9 26.20* 187.72** 0.0213 0.0290 9.57 262.17** 0.0340 0.1407 27.16* 744.20**
Residual 4724.3 1439.58 0.0061 0.0021 0.0034 0.0015
LoF 1432.4 648.89 0.29 ns 0.54 ns 0.0016 0.0018 0.24 ns 5.63 ns 0.0009 0.0011 0.25 ns 2.01 ns
PE 3291.9 790.69 0.0044 0.0002 0.0025 0.0003
Total 115749.8 80116.7 0.0538 0.0344 0.1052 0.1479
Pred. R2 0.9592 0.9820 0.8870 0.9391 0.9672 0.9897
Adj. R2 0.8857 0.9496 0.6836 0.8297 0.9083 0.9713

XA (Time, min), XB (Amplitude, %), XC (Ethanol, %). ns not significant (p > 0.05), * p < 0.05, ** p < 0.01, *** p < 0.001.