| CMC |
carboxymethyl chitosan |
| PAMAM |
poly(amidoamine) |
|
Nomenclature
|
|
C
|
the constant proportional to the extent of the boundary layer thickness (mg·g−1) |
|
C
0
|
the initial concentrations of the metal ion (mg∙L−1) |
|
C
e
|
the equilibrium concentrations of the metal ion (mg∙L−1), |
|
E
DR
|
the mean free energy of adsorption |
|
k
1
|
the rate constants of pseudo-first-order model (min−1), |
|
k
2
|
the rate constants of pseudo-second-order model (g∙mg−1∙min−1) |
|
k
int
|
the rate constants of intraparticle diffusion kinetics model (mg·g−1·min−0.5) |
|
K
d
|
the distribution coefficient (mL∙g−1) |
|
|
the distribution coefficients of uranyl ion |
|
|
the distribution coefficients of other ions |
|
K
F
|
Freundlich constants, indicating adsorption intensity |
|
K
L
|
the Langmuir adsorption equilibrium constant (L·mg−1) |
|
m
|
the amount of the sorbent (g) |
|
n
|
Freundlich constants, indicating adsorption capacity |
|
q
e
|
the amount of adsorption at equilibrium (mg∙g−1) |
|
q
e(U)
|
the adsorption capacity of uranium (mg·g−1) |
|
q
e(Total)
|
the total amount of adsorption for all multi-ions (mg∙g−1). |
|
q
DR
|
the theoretical adsorption capacity (mol·g−1) |
|
q
m
|
the maximum or saturated amount of adsorption (mg∙g−1) |
|
q
t
|
U(VI) adsorption capacity at t (mg·g−1) |
| R |
the ideal gas constant (8.314 kJ·mol−1 K−1) |
|
R
L
|
the dimensionless constant separation factor |
|
S
U
|
degree of selectivity of the adsorbent towards uranium |
|
S
U(VI)/M(x)
|
the selectivity coefficient of uranyl ions relative to competing ions |
|
S
r
|
the relative selectivity coefficient |
|
t
|
the adsorption time (min) |
|
T
|
the absolute temperature (K). |
|
V
|
the volume of the solution (L) |
|
Greek letters
|
|
β
|
the constant associated with the adsorption energy (mol2·kJ−2) |
|
ε
|
the Polanyi potential |
| ΔS° |
standard entropy (J·mol−1·K−1) |
| ΔH° |
standard enthalpy (kJ·mol−1) |
| ΔG° |
standard Gibbs free energy (kJ·mol−1) |