Crystallite size and strain values of GDC-00, -10, -20, and -30 ceramicsa.
System | Method | Scherrer | Monshi | W–H (UDM) | SSP | H–W |
---|---|---|---|---|---|---|
GDC-00 | D (nm) | 69.7096 | 73.2469 | 72.6126 | 70.7602 | 78.7724 |
ε (×10−3) | 0.0394 | — | −0.0170 | −0.1641 | −1.0646 | |
GDC-10 | D (nm) | 11.6418 | 63.9861 | 60.5633 | 64.8084 | 71.9114 |
ε (×10−3) | 0.0075 | — | −0.1734 | −0.1809 | −1.1738 | |
GDC-20 | D (nm) | — | 81.8293 | 294.8843 | 185.3047 | 205.8943 |
ε (×10−3) | 0.6150 | — | 2.5 | 1.4885 | 9.6591 | |
GDC-30 | D (nm) | 102.5623 | 29.6531 | 24.0781 | 28.5370 | 31.7365 |
ε (×10−3) | 0.2352 | — | −1.51 | −0.8737 | −5.6698 |
Compressive stress, denoted by a negative ε value for GDC, results from the assertion of equal and opposing pressures, which in turn causes the crystalline structure to shrink.32,33