Fig. 9. Reactivity of complexes [(Me21)2Cu][BF4] and [Me21Cu][BF4]2 and corresponding Cu(ii)–MOF system UiO-67-[1Cu][BF4]2-ML compared to the Cu(i) and Cu(ii) tetrafluoroborate salts for the oxidative conversion of cyclohexane. The graph represents an average of three replicates. C-based product selectivity (left-Y axis) and average turnover (purple line, right-Y axis) of the different catalysts towards oxidation products data (Cy–OOH + Cy–OH + Cy O) at 30, and 240 min are shown as pairs of stacked bars from left to right.
