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Solid-state structure of compound 2 with ellipsoids at 30% of probability. Hydrogen atoms are omitted for clarity. The dihedral angle between planes formed by N1–Ti1–N2 and N1–C1–C2-N2 is 14.1°. Selected average bond distances (Å) and angles (°): Ti–N 1.970(5), Ti–O 2.208(1), Ti–Cl 2.364(9), N–Ti–N 80.48(9), O–Ti–O 95.1(1), Cl–Ti–Cl 162.08(3).
