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Solid-state structure of compound 3 with ellipsoids at 30% of probability. Hydrogen atoms are omitted for clarity. Selected average bond distances (Å) and angles (°): Ti–N 2.01(1), Ti–O 2.139(8), Ti–Cl 2.53(5), Na–Cl 2.78(1), Na-centroid 2.589(3) and 2.644(3), O2–Ti1–Cl2 163.07(7), N1–Ti1–N2 80.4(1), Cl1–Ti1–Cl3 84.81(3), Cl1–Ti2–N4 175.41(8), O1–Ti2–N3 102.0(2), Cl2–Ti2–Cl3 77.63(3).
